CO2 Conversion: The Potential of Porous–Organic Polymers (POPs) for the cycloaddition of CO2 and epoxides

Mohamed Al Kordi; Lukasz Jan Weselinski; Valerio D’Elia; Samir Barman; Amandine Cadiau; Mohamed N. Hedhili; Amy Cairns; Rasha AbdulHalim; Jean-Marie Basset; Mohamed Eddaoudi

doi:10.1039/C5TA09321J

CO2 Conversion: The Potential of Porous–Organic Polymers (POPs) for the cycloaddition of CO2 and epoxides

Mohamed Al Kordi, Lukasz Jan Weselinski, Valerio D’Elia, Samir Barman, Amandine Cadiau, Mohamed N. Hedhili, Amy Cairns, Rasha AbdulHalim, Jean-Marie Basset, Mohamed Eddaoudi

Research output: Contribution to journal › Article › peer-review

111 Scopus citations

Abstract

Novel porous organic polymers (POPs) have been synthesized using functionalized Cr and Co-salen complexes as molecular building blocks. The integration of metalosalen catalysts into the porous polymers backbone permits the successful utilization of the materials as solid-state catalysts for CO2-epoxide cycloadditions reactions with excellent catalytic performance under mild conditions of temperature and pressure. The catalyst proved to be fully recyclable and robust thus showing the potential of POPs as smart functional materials for the heterogenization of key catalytic elements.

Original language	English (US)
Pages (from-to)	7453-7460
Number of pages	8
Journal	J. Mater. Chem. A
Volume	4
Issue number	19
DOIs	https://doi.org/10.1039/C5TA09321J
State	Published - 2016

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Research reported in this publication was supported by the
King Abdullah University of Science and Technology
(KAUST).

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10.1039/C5TA09321J

https://repository.kaust.edu.sa/bitstream/10754/604374/1/c5ta09321j.pdf

Cite this

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title = "CO2 Conversion: The Potential of Porous–Organic Polymers (POPs) for the cycloaddition of CO2 and epoxides",

abstract = "Novel porous organic polymers (POPs) have been synthesized using functionalized Cr and Co-salen complexes as molecular building blocks. The integration of metalosalen catalysts into the porous polymers backbone permits the successful utilization of the materials as solid-state catalysts for CO2-epoxide cycloadditions reactions with excellent catalytic performance under mild conditions of temperature and pressure. The catalyst proved to be fully recyclable and robust thus showing the potential of POPs as smart functional materials for the heterogenization of key catalytic elements.",

author = "{Al Kordi}, Mohamed and Weselinski, {Lukasz Jan} and Valerio D{\textquoteright}Elia and Samir Barman and Amandine Cadiau and Hedhili, {Mohamed N.} and Amy Cairns and Rasha AbdulHalim and Jean-Marie Basset and Mohamed Eddaoudi",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Research reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).",

year = "2016",

doi = "10.1039/C5TA09321J",

language = "English (US)",

volume = "4",

pages = "7453--7460",

journal = "J. Mater. Chem. A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - CO2 Conversion: The Potential of Porous–Organic Polymers (POPs) for the cycloaddition of CO2 and epoxides

AU - Al Kordi, Mohamed

AU - Weselinski, Lukasz Jan

AU - D’Elia, Valerio

AU - Barman, Samir

AU - Cadiau, Amandine

AU - Hedhili, Mohamed N.

AU - Cairns, Amy

AU - AbdulHalim, Rasha

AU - Basset, Jean-Marie

AU - Eddaoudi, Mohamed

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Research reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).

PY - 2016

Y1 - 2016

N2 - Novel porous organic polymers (POPs) have been synthesized using functionalized Cr and Co-salen complexes as molecular building blocks. The integration of metalosalen catalysts into the porous polymers backbone permits the successful utilization of the materials as solid-state catalysts for CO2-epoxide cycloadditions reactions with excellent catalytic performance under mild conditions of temperature and pressure. The catalyst proved to be fully recyclable and robust thus showing the potential of POPs as smart functional materials for the heterogenization of key catalytic elements.

AB - Novel porous organic polymers (POPs) have been synthesized using functionalized Cr and Co-salen complexes as molecular building blocks. The integration of metalosalen catalysts into the porous polymers backbone permits the successful utilization of the materials as solid-state catalysts for CO2-epoxide cycloadditions reactions with excellent catalytic performance under mild conditions of temperature and pressure. The catalyst proved to be fully recyclable and robust thus showing the potential of POPs as smart functional materials for the heterogenization of key catalytic elements.

UR - http://hdl.handle.net/10754/604374

UR - http://pubs.rsc.org/en/Content/ArticleLanding/2016/TA/C5TA09321J

UR - http://www.scopus.com/inward/record.url?scp=84969776484&partnerID=8YFLogxK

U2 - 10.1039/C5TA09321J

DO - 10.1039/C5TA09321J

M3 - Article

SN - 2050-7488

VL - 4

SP - 7453

EP - 7460

JO - J. Mater. Chem. A

JF - J. Mater. Chem. A

IS - 19

ER -

CO2 Conversion: The Potential of Porous–Organic Polymers (POPs) for the cycloaddition of CO2 and epoxides

Abstract

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