CO oxidation catalyzed by ag nanoparticles supported on SnO/CeO2

Inayatali Khan; Nida K M Sajid; Amin Badshah; Muhammad Hamid Sarwar Wattoo; Dalaver H. Anjum; Muhammad Amtiaz Nadeem

doi:10.5935/0103-5053.20150028

CO oxidation catalyzed by ag nanoparticles supported on SnO/CeO2

Inayatali Khan, Nida K M Sajid, Amin Badshah, Muhammad Hamid Sarwar Wattoo, Dalaver H. Anjum, Muhammad Amtiaz Nadeem

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Ag-Sn/CeO2 catalysts were synthesized by the co-precipitation method with different Ag-Sn wt.% loadings and were tested for the oxidation of CO. The catalysts were characterized by powder X-ray diffractometry (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), energy dispersive X-ray spectroscopy (EDS), and selected area electron diffraction (SAED) techniques. UV-Vis measurements were carried out to elucidate the ionic states of the silver particles, and the temperature-programmed reduction (TPR) technique was employed to check the reduction temperature of the catalyst supported on CeO2. There are peaks for silver crystallites in the X-ray diffraction patterns and the presence of SnO was not well evidenced by the XRD technique due to sintering inside the 3D array channels of CeO2 during the calcination process. The Ag-Sn/CeO2 (4%) catalyst was the most efficient and exhibited 100% CO oxidation at 100 °C due to small particle size and strong electronic interaction with the SnO/CeO2 support. © 2015 Sociedade Brasileira de Química.

Original language	English (US)
Pages (from-to)	695-704
Number of pages	10
Journal	Journal of the Brazilian Chemical Society
Volume	26
Issue number	4
DOIs	https://doi.org/10.5935/0103-5053.20150028
State	Published - 2015

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work was supported by the Higher Education Commission (HEC) of Pakistan (No. 20-1638/ R&D/09/2900). The authors thank PhD Dalaver Hussain Anjum (KAUST Saudi Arabia) for high resolution TEM and SAED analyses.

ASJC Scopus subject areas

General Chemistry

Access to Document

10.5935/0103-5053.20150028

Cite this

@article{ca231f4592904f92b85c98297aabbde7,

title = "CO oxidation catalyzed by ag nanoparticles supported on SnO/CeO2",

abstract = "Ag-Sn/CeO2 catalysts were synthesized by the co-precipitation method with different Ag-Sn wt.% loadings and were tested for the oxidation of CO. The catalysts were characterized by powder X-ray diffractometry (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), energy dispersive X-ray spectroscopy (EDS), and selected area electron diffraction (SAED) techniques. UV-Vis measurements were carried out to elucidate the ionic states of the silver particles, and the temperature-programmed reduction (TPR) technique was employed to check the reduction temperature of the catalyst supported on CeO2. There are peaks for silver crystallites in the X-ray diffraction patterns and the presence of SnO was not well evidenced by the XRD technique due to sintering inside the 3D array channels of CeO2 during the calcination process. The Ag-Sn/CeO2 (4%) catalyst was the most efficient and exhibited 100% CO oxidation at 100 °C due to small particle size and strong electronic interaction with the SnO/CeO2 support. {\textcopyright} 2015 Sociedade Brasileira de Qu{\'i}mica.",

author = "Inayatali Khan and Sajid, {Nida K M} and Amin Badshah and Wattoo, {Muhammad Hamid Sarwar} and Anjum, {Dalaver H.} and Nadeem, {Muhammad Amtiaz}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Higher Education Commission (HEC) of Pakistan (No. 20-1638/ R&D/09/2900). The authors thank PhD Dalaver Hussain Anjum (KAUST Saudi Arabia) for high resolution TEM and SAED analyses.",

year = "2015",

doi = "10.5935/0103-5053.20150028",

language = "English (US)",

volume = "26",

pages = "695--704",

journal = "Journal of the Brazilian Chemical Society",

issn = "0103-5053",

publisher = "Sociedade Brasileira de Quimica",

number = "4",

}

TY - JOUR

T1 - CO oxidation catalyzed by ag nanoparticles supported on SnO/CeO2

AU - Khan, Inayatali

AU - Sajid, Nida K M

AU - Badshah, Amin

AU - Wattoo, Muhammad Hamid Sarwar

AU - Anjum, Dalaver H.

AU - Nadeem, Muhammad Amtiaz

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Higher Education Commission (HEC) of Pakistan (No. 20-1638/ R&D/09/2900). The authors thank PhD Dalaver Hussain Anjum (KAUST Saudi Arabia) for high resolution TEM and SAED analyses.

PY - 2015

Y1 - 2015

N2 - Ag-Sn/CeO2 catalysts were synthesized by the co-precipitation method with different Ag-Sn wt.% loadings and were tested for the oxidation of CO. The catalysts were characterized by powder X-ray diffractometry (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), energy dispersive X-ray spectroscopy (EDS), and selected area electron diffraction (SAED) techniques. UV-Vis measurements were carried out to elucidate the ionic states of the silver particles, and the temperature-programmed reduction (TPR) technique was employed to check the reduction temperature of the catalyst supported on CeO2. There are peaks for silver crystallites in the X-ray diffraction patterns and the presence of SnO was not well evidenced by the XRD technique due to sintering inside the 3D array channels of CeO2 during the calcination process. The Ag-Sn/CeO2 (4%) catalyst was the most efficient and exhibited 100% CO oxidation at 100 °C due to small particle size and strong electronic interaction with the SnO/CeO2 support. © 2015 Sociedade Brasileira de Química.

AB - Ag-Sn/CeO2 catalysts were synthesized by the co-precipitation method with different Ag-Sn wt.% loadings and were tested for the oxidation of CO. The catalysts were characterized by powder X-ray diffractometry (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), energy dispersive X-ray spectroscopy (EDS), and selected area electron diffraction (SAED) techniques. UV-Vis measurements were carried out to elucidate the ionic states of the silver particles, and the temperature-programmed reduction (TPR) technique was employed to check the reduction temperature of the catalyst supported on CeO2. There are peaks for silver crystallites in the X-ray diffraction patterns and the presence of SnO was not well evidenced by the XRD technique due to sintering inside the 3D array channels of CeO2 during the calcination process. The Ag-Sn/CeO2 (4%) catalyst was the most efficient and exhibited 100% CO oxidation at 100 °C due to small particle size and strong electronic interaction with the SnO/CeO2 support. © 2015 Sociedade Brasileira de Química.

UR - http://hdl.handle.net/10754/563959

UR - http://www.crossref.org/iPage?doi=10.5935%2F0103-5053.20150028

UR - http://www.scopus.com/inward/record.url?scp=84926137768&partnerID=8YFLogxK

U2 - 10.5935/0103-5053.20150028

DO - 10.5935/0103-5053.20150028

M3 - Article

SN - 0103-5053

VL - 26

SP - 695

EP - 704

JO - Journal of the Brazilian Chemical Society

JF - Journal of the Brazilian Chemical Society

IS - 4

ER -

CO oxidation catalyzed by ag nanoparticles supported on SnO/CeO2

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this