CO 2 adsorption studies on Prussian blue analogues

F. Karadas; H. El-Faki; E. Deniz; C. T. Yavuz; S. Aparicio; M. Atilhan

doi:10.1016/j.micromeso.2012.06.019

CO 2 adsorption studies on Prussian blue analogues

F. Karadas, H. El-Faki, E. Deniz, C. T. Yavuz, S. Aparicio, M. Atilhan

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44 Scopus citations

Abstract

Carbon dioxide (CO 2) adsorption capacities of several Prussian blue (PB) analogues have been studied using the state-of-the-art Rubotherm® sorption apparatus to obtain adsorption and desorption isotherms of these compounds up to 50 bar. The analogues were prepared by simply reacting a [M(CN) 6] 3- (MCo, Fe) solution with solutions of M 2+ (MMn, Fe, Co, Ni, Cu) metal ions. Characterization of the studied samples has been performed by using a combination of powder XRD, TGA, FTIR, and CHN elemental analysis. Adsorption capacities of PB analogues calculated with theoretical calculations, using Monte Carlo approach, have also been compared with the experimental study, and used to discuss the molecular mechanism of adsorption. © 2012 Elsevier Inc. All rights reserved.

Original language	English (US)
Pages (from-to)	91-97
Number of pages	7
Journal	Microporous and Mesoporous Materials
Volume	162
DOIs	https://doi.org/10.1016/j.micromeso.2012.06.019
State	Published - Nov 1 2012
Externally published	Yes

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Generated from Scopus record by KAUST IRTS on 2021-03-16

ASJC Scopus subject areas

Mechanics of Materials
General Materials Science
General Chemistry
Condensed Matter Physics

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title = "CO 2 adsorption studies on Prussian blue analogues",

abstract = "Carbon dioxide (CO 2) adsorption capacities of several Prussian blue (PB) analogues have been studied using the state-of-the-art Rubotherm{\textregistered} sorption apparatus to obtain adsorption and desorption isotherms of these compounds up to 50 bar. The analogues were prepared by simply reacting a [M(CN) 6] 3- (MCo, Fe) solution with solutions of M 2+ (MMn, Fe, Co, Ni, Cu) metal ions. Characterization of the studied samples has been performed by using a combination of powder XRD, TGA, FTIR, and CHN elemental analysis. Adsorption capacities of PB analogues calculated with theoretical calculations, using Monte Carlo approach, have also been compared with the experimental study, and used to discuss the molecular mechanism of adsorption. {\textcopyright} 2012 Elsevier Inc. All rights reserved.",

author = "F. Karadas and H. El-Faki and E. Deniz and Yavuz, {C. T.} and S. Aparicio and M. Atilhan",

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doi = "10.1016/j.micromeso.2012.06.019",

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T1 - CO 2 adsorption studies on Prussian blue analogues

AU - Karadas, F.

AU - El-Faki, H.

AU - Deniz, E.

AU - Yavuz, C. T.

AU - Aparicio, S.

AU - Atilhan, M.

N1 - Generated from Scopus record by KAUST IRTS on 2021-03-16

PY - 2012/11/1

Y1 - 2012/11/1

N2 - Carbon dioxide (CO 2) adsorption capacities of several Prussian blue (PB) analogues have been studied using the state-of-the-art Rubotherm® sorption apparatus to obtain adsorption and desorption isotherms of these compounds up to 50 bar. The analogues were prepared by simply reacting a [M(CN) 6] 3- (MCo, Fe) solution with solutions of M 2+ (MMn, Fe, Co, Ni, Cu) metal ions. Characterization of the studied samples has been performed by using a combination of powder XRD, TGA, FTIR, and CHN elemental analysis. Adsorption capacities of PB analogues calculated with theoretical calculations, using Monte Carlo approach, have also been compared with the experimental study, and used to discuss the molecular mechanism of adsorption. © 2012 Elsevier Inc. All rights reserved.

AB - Carbon dioxide (CO 2) adsorption capacities of several Prussian blue (PB) analogues have been studied using the state-of-the-art Rubotherm® sorption apparatus to obtain adsorption and desorption isotherms of these compounds up to 50 bar. The analogues were prepared by simply reacting a [M(CN) 6] 3- (MCo, Fe) solution with solutions of M 2+ (MMn, Fe, Co, Ni, Cu) metal ions. Characterization of the studied samples has been performed by using a combination of powder XRD, TGA, FTIR, and CHN elemental analysis. Adsorption capacities of PB analogues calculated with theoretical calculations, using Monte Carlo approach, have also been compared with the experimental study, and used to discuss the molecular mechanism of adsorption. © 2012 Elsevier Inc. All rights reserved.

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U2 - 10.1016/j.micromeso.2012.06.019

DO - 10.1016/j.micromeso.2012.06.019

M3 - Article

SN - 1387-1811

VL - 162

SP - 91

EP - 97

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

CO 2 adsorption studies on Prussian blue analogues

Abstract

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