Chromatography of functional polymers: A new approach to the characterization of reactive polymers obtained by chemical modification

Miroslav Petro; Frantisek Svec; Jean M.J. Fréchet; Shah A. Haque; Hsien C. Wang

doi:10.1002/(SICI)1099-0518(199705)35:7<1173::AID-POLA3>3.0.CO;2-3

Chromatography of functional polymers: A new approach to the characterization of reactive polymers obtained by chemical modification

Miroslav Petro, Frantisek Svec, Jean M.J. Fréchet^*, Shah A. Haque, Hsien C. Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

High-performance liquid chromatography (HPLC) has been used to complement size-exclusion (gel permeation) chromatography (SEC) for the characterization of functional polymers. Whereas SEC is unable to detect compositional changes, HPLC in an appropriate interacting medium can provide detailed information on compositional changes occurring during chemical modification of a polymer. The method has been demonstrated using a normal-phase column consisting of porous monodisperse 10 μm poly(2,3-dihydroxypropyl methacrylate-co-ethylene dimethacrylate) beads that have a homogeneous coverage of aliphatic hydroxyl groups for the analysis of brominated poly(isobutylene-co-4-methylstyrene). Differences of well below 1 mol % of bromomethylstyrene units are easily detected and quantified.

Original language	English (US)
Pages (from-to)	1173-1180
Number of pages	8
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	35
Issue number	7
DOIs	https://doi.org/10.1002/(SICI)1099-0518(199705)35:7<1173::AID-POLA3>3.0.CO;2-3
State	Published - May 1997
Externally published	Yes

Keywords

Bromination
Chemical composition distribution
HPLC
Liquid chromatography
Monodisperse particles
Poly(isobutylene-co-4-methylstyrene)
Porous polymer beads

ASJC Scopus subject areas

Polymers and Plastics
Organic Chemistry
Materials Chemistry

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10.1002/(SICI)1099-0518(199705)35:7<1173::AID-POLA3>3.0.CO;2-3

Cite this

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title = "Chromatography of functional polymers: A new approach to the characterization of reactive polymers obtained by chemical modification",

abstract = "High-performance liquid chromatography (HPLC) has been used to complement size-exclusion (gel permeation) chromatography (SEC) for the characterization of functional polymers. Whereas SEC is unable to detect compositional changes, HPLC in an appropriate interacting medium can provide detailed information on compositional changes occurring during chemical modification of a polymer. The method has been demonstrated using a normal-phase column consisting of porous monodisperse 10 μm poly(2,3-dihydroxypropyl methacrylate-co-ethylene dimethacrylate) beads that have a homogeneous coverage of aliphatic hydroxyl groups for the analysis of brominated poly(isobutylene-co-4-methylstyrene). Differences of well below 1 mol % of bromomethylstyrene units are easily detected and quantified.",

keywords = "Bromination, Chemical composition distribution, HPLC, Liquid chromatography, Monodisperse particles, Poly(isobutylene-co-4-methylstyrene), Porous polymer beads",

author = "Miroslav Petro and Frantisek Svec and Fr{\'e}chet, {Jean M.J.} and Haque, {Shah A.} and Wang, {Hsien C.}",

year = "1997",

month = may,

doi = "10.1002/(SICI)1099-0518(199705)35:7<1173::AID-POLA3>3.0.CO;2-3",

language = "English (US)",

volume = "35",

pages = "1173--1180",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley & Sons Inc.",

number = "7",

}

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T1 - Chromatography of functional polymers

T2 - A new approach to the characterization of reactive polymers obtained by chemical modification

AU - Petro, Miroslav

AU - Svec, Frantisek

AU - Fréchet, Jean M.J.

AU - Haque, Shah A.

AU - Wang, Hsien C.

PY - 1997/5

Y1 - 1997/5

N2 - High-performance liquid chromatography (HPLC) has been used to complement size-exclusion (gel permeation) chromatography (SEC) for the characterization of functional polymers. Whereas SEC is unable to detect compositional changes, HPLC in an appropriate interacting medium can provide detailed information on compositional changes occurring during chemical modification of a polymer. The method has been demonstrated using a normal-phase column consisting of porous monodisperse 10 μm poly(2,3-dihydroxypropyl methacrylate-co-ethylene dimethacrylate) beads that have a homogeneous coverage of aliphatic hydroxyl groups for the analysis of brominated poly(isobutylene-co-4-methylstyrene). Differences of well below 1 mol % of bromomethylstyrene units are easily detected and quantified.

AB - High-performance liquid chromatography (HPLC) has been used to complement size-exclusion (gel permeation) chromatography (SEC) for the characterization of functional polymers. Whereas SEC is unable to detect compositional changes, HPLC in an appropriate interacting medium can provide detailed information on compositional changes occurring during chemical modification of a polymer. The method has been demonstrated using a normal-phase column consisting of porous monodisperse 10 μm poly(2,3-dihydroxypropyl methacrylate-co-ethylene dimethacrylate) beads that have a homogeneous coverage of aliphatic hydroxyl groups for the analysis of brominated poly(isobutylene-co-4-methylstyrene). Differences of well below 1 mol % of bromomethylstyrene units are easily detected and quantified.

KW - Bromination

KW - Chemical composition distribution

KW - HPLC

KW - Liquid chromatography

KW - Monodisperse particles

KW - Poly(isobutylene-co-4-methylstyrene)

KW - Porous polymer beads

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U2 - 10.1002/(SICI)1099-0518(199705)35:7<1173::AID-POLA3>3.0.CO;2-3

DO - 10.1002/(SICI)1099-0518(199705)35:7<1173::AID-POLA3>3.0.CO;2-3

M3 - Article

AN - SCOPUS:0031145098

SN - 0887-624X

VL - 35

SP - 1173

EP - 1180

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 7

ER -

Chromatography of functional polymers: A new approach to the characterization of reactive polymers obtained by chemical modification

Abstract

Keywords

ASJC Scopus subject areas

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