Chloromethylation as a functionalisation pathway for metal-organic frameworks

Maarten Goesten; Karthick B. Sai Sankar Gupta; Enrique V. Ramos-Fernandez; Hossein Khajavi; Jorge Gascon; Freek Kapteijn

doi:10.1039/c2ce06594k

Chloromethylation as a functionalisation pathway for metal-organic frameworks

Maarten Goesten^*, Karthick B. Sai Sankar Gupta, Enrique V. Ramos-Fernandez, Hossein Khajavi, Jorge Gascon, Freek Kapteijn

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

A mild and safe chloromethylation of metal-organic frameworks is presented. After this post-synthetic functionalization, chlorine can be substituted by a wide range of moieties to obtain various multifunctional materials. The method can in principle be extended to coordination polymers with exposed aromatic rings.

Original language	English (US)
Pages (from-to)	4109-4111
Number of pages	3
Journal	CRYSTENGCOMM
Volume	14
Issue number	12
DOIs	https://doi.org/10.1039/c2ce06594k
State	Published - Jun 21 2012
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1039/c2ce06594k

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title = "Chloromethylation as a functionalisation pathway for metal-organic frameworks",

abstract = "A mild and safe chloromethylation of metal-organic frameworks is presented. After this post-synthetic functionalization, chlorine can be substituted by a wide range of moieties to obtain various multifunctional materials. The method can in principle be extended to coordination polymers with exposed aromatic rings.",

author = "Maarten Goesten and {Sai Sankar Gupta}, {Karthick B.} and Ramos-Fernandez, {Enrique V.} and Hossein Khajavi and Jorge Gascon and Freek Kapteijn",

year = "2012",

month = jun,

day = "21",

doi = "10.1039/c2ce06594k",

language = "English (US)",

volume = "14",

pages = "4109--4111",

journal = "CRYSTENGCOMM",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

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T1 - Chloromethylation as a functionalisation pathway for metal-organic frameworks

AU - Goesten, Maarten

AU - Sai Sankar Gupta, Karthick B.

AU - Ramos-Fernandez, Enrique V.

AU - Khajavi, Hossein

AU - Gascon, Jorge

AU - Kapteijn, Freek

PY - 2012/6/21

Y1 - 2012/6/21

N2 - A mild and safe chloromethylation of metal-organic frameworks is presented. After this post-synthetic functionalization, chlorine can be substituted by a wide range of moieties to obtain various multifunctional materials. The method can in principle be extended to coordination polymers with exposed aromatic rings.

AB - A mild and safe chloromethylation of metal-organic frameworks is presented. After this post-synthetic functionalization, chlorine can be substituted by a wide range of moieties to obtain various multifunctional materials. The method can in principle be extended to coordination polymers with exposed aromatic rings.

UR - http://www.scopus.com/inward/record.url?scp=84862292958&partnerID=8YFLogxK

U2 - 10.1039/c2ce06594k

DO - 10.1039/c2ce06594k

M3 - Article

AN - SCOPUS:84862292958

SN - 1466-8033

VL - 14

SP - 4109

EP - 4111

JO - CRYSTENGCOMM

JF - CRYSTENGCOMM

IS - 12

ER -

Chloromethylation as a functionalisation pathway for metal-organic frameworks

Abstract

ASJC Scopus subject areas

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