Chemoselective Luche-Type Reduction of α,β-Unsaturated Ketones by Magnesium Catalysis

Yoon Kyung Jang; Marc Magre; Magnus Rueping

doi:10.1021/acs.orglett.9b03131

Chemoselective Luche-Type Reduction of α,β-Unsaturated Ketones by Magnesium Catalysis

Yoon Kyung Jang, Marc Magre, Magnus Rueping

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Abstract

The chemoselective reduction of α,β-unsaturated ketones by use of an economic and readily available Mg catalyst has been developed. Excellent yields for a wide range of ketones have been achieved under mild reaction conditions, short times, and low catalyst loadings (0.2-0.5 mol %).

Original language	English (US)
Pages (from-to)	8349-8352
Number of pages	4
Journal	Organic Letters
Volume	21
Issue number	20
DOIs	https://doi.org/10.1021/acs.orglett.9b03131
State	Published - Oct 7 2019

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title = "Chemoselective Luche-Type Reduction of α,β-Unsaturated Ketones by Magnesium Catalysis",

abstract = "The chemoselective reduction of α,β-unsaturated ketones by use of an economic and readily available Mg catalyst has been developed. Excellent yields for a wide range of ketones have been achieved under mild reaction conditions, short times, and low catalyst loadings (0.2-0.5 mol %).",

author = "Jang, {Yoon Kyung} and Marc Magre and Magnus Rueping",

note = "KAUST Repository Item: Exported on 2020-10-01",

year = "2019",

month = oct,

day = "7",

doi = "10.1021/acs.orglett.9b03131",

language = "English (US)",

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journal = "Organic Letters",

issn = "1523-7060",

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T1 - Chemoselective Luche-Type Reduction of α,β-Unsaturated Ketones by Magnesium Catalysis

AU - Jang, Yoon Kyung

AU - Magre, Marc

AU - Rueping, Magnus

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2019/10/7

Y1 - 2019/10/7

N2 - The chemoselective reduction of α,β-unsaturated ketones by use of an economic and readily available Mg catalyst has been developed. Excellent yields for a wide range of ketones have been achieved under mild reaction conditions, short times, and low catalyst loadings (0.2-0.5 mol %).

AB - The chemoselective reduction of α,β-unsaturated ketones by use of an economic and readily available Mg catalyst has been developed. Excellent yields for a wide range of ketones have been achieved under mild reaction conditions, short times, and low catalyst loadings (0.2-0.5 mol %).

UR - http://hdl.handle.net/10754/659501

UR - http://pubs.acs.org/doi/10.1021/acs.orglett.9b03131

UR - http://www.scopus.com/inward/record.url?scp=85073157694&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.9b03131

DO - 10.1021/acs.orglett.9b03131

M3 - Article

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SN - 1523-7060

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SP - 8349

EP - 8352

JO - Organic Letters

JF - Organic Letters

IS - 20

ER -

Chemoselective Luche-Type Reduction of α,β-Unsaturated Ketones by Magnesium Catalysis

Abstract

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