Characterization of proton-conducting organic-inorganic polymeric materials by ASAXS

Luís A.S.De A. Prado; G. Goerigk; M. L. Ponce; V. M. Garamus; H. Wittich; R. Willumeit; K. Schulte; S. P. Nunes

doi:10.1002/polb.20576

Characterization of proton-conducting organic-inorganic polymeric materials by ASAXS

Luís A.S.De A. Prado^*, G. Goerigk, M. L. Ponce, V. M. Garamus, H. Wittich, R. Willumeit, K. Schulte, S. P. Nunes

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The distribution of ZrO₂ and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small-angle X-ray scattering (ASAXS). Scattering curves were obtained using X-ray energies near the Zr and W absorption edges, allowing the independent analysis of the distribution of ZrO₂ and PTA in the sample. The interaction between both inorganic components improved their dispersion considerably when compared with films containing just one of the additives. The synergism was correlated to previous investigations concerning proton conductivity and permeability of the membranes developed for direct methanol fuel cell.

Original language	English (US)
Pages (from-to)	2981-2992
Number of pages	12
Journal	Journal of Polymer Science, Part B: Polymer Physics
Volume	43
Issue number	21
DOIs	https://doi.org/10.1002/polb.20576
State	Published - Nov 1 2005
Externally published	Yes

Keywords

Anomalous small-angle X-ray scattering
Organic-inorganic hybrid materials
Proton-conducting membranes

ASJC Scopus subject areas

Condensed Matter Physics
Physical and Theoretical Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/polb.20576

Cite this

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title = "Characterization of proton-conducting organic-inorganic polymeric materials by ASAXS",

abstract = "The distribution of ZrO2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small-angle X-ray scattering (ASAXS). Scattering curves were obtained using X-ray energies near the Zr and W absorption edges, allowing the independent analysis of the distribution of ZrO2 and PTA in the sample. The interaction between both inorganic components improved their dispersion considerably when compared with films containing just one of the additives. The synergism was correlated to previous investigations concerning proton conductivity and permeability of the membranes developed for direct methanol fuel cell.",

keywords = "Anomalous small-angle X-ray scattering, Organic-inorganic hybrid materials, Proton-conducting membranes",

author = "Prado, {Lu{\'i}s A.S.De A.} and G. Goerigk and Ponce, {M. L.} and Garamus, {V. M.} and H. Wittich and R. Willumeit and K. Schulte and Nunes, {S. P.}",

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month = nov,

day = "1",

doi = "10.1002/polb.20576",

language = "English (US)",

volume = "43",

pages = "2981--2992",

journal = "Journal of Polymer Science, Part B: Polymer Physics",

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publisher = "John Wiley & Sons Inc.",

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TY - JOUR

T1 - Characterization of proton-conducting organic-inorganic polymeric materials by ASAXS

AU - Prado, Luís A.S.De A.

AU - Goerigk, G.

AU - Ponce, M. L.

AU - Garamus, V. M.

AU - Wittich, H.

AU - Willumeit, R.

AU - Schulte, K.

AU - Nunes, S. P.

PY - 2005/11/1

Y1 - 2005/11/1

N2 - The distribution of ZrO2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small-angle X-ray scattering (ASAXS). Scattering curves were obtained using X-ray energies near the Zr and W absorption edges, allowing the independent analysis of the distribution of ZrO2 and PTA in the sample. The interaction between both inorganic components improved their dispersion considerably when compared with films containing just one of the additives. The synergism was correlated to previous investigations concerning proton conductivity and permeability of the membranes developed for direct methanol fuel cell.

AB - The distribution of ZrO2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small-angle X-ray scattering (ASAXS). Scattering curves were obtained using X-ray energies near the Zr and W absorption edges, allowing the independent analysis of the distribution of ZrO2 and PTA in the sample. The interaction between both inorganic components improved their dispersion considerably when compared with films containing just one of the additives. The synergism was correlated to previous investigations concerning proton conductivity and permeability of the membranes developed for direct methanol fuel cell.

KW - Anomalous small-angle X-ray scattering

KW - Organic-inorganic hybrid materials

KW - Proton-conducting membranes

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U2 - 10.1002/polb.20576

DO - 10.1002/polb.20576

M3 - Article

AN - SCOPUS:27844603327

SN - 0887-6266

VL - 43

SP - 2981

EP - 2992

JO - Journal of Polymer Science, Part B: Polymer Physics

JF - Journal of Polymer Science, Part B: Polymer Physics

IS - 21

ER -

Characterization of proton-conducting organic-inorganic polymeric materials by ASAXS

Abstract

Keywords

ASJC Scopus subject areas

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