Abstract
The term miktoarm stars (coming from the Greek word μιτσ meaning mixed) was adopted in 1992 by our group for star polymers with either chemical (e.g., A2B), molecular weight (e.g., A2A′), topological (e.g., (AB)2-junction-(BA)2), or functional group (e.g., AFA2) asymmetry. The first μ-stars synthesized by anionic polymerization, on the one hand, guided polymer chemists working with other types of polymerization techniques towards this direction and, on the other hand, helped polymer physicists to carry out experiments and develop theories on the influence of the architecture on the morphology of block copolymers. Synthetic strategies based on anionic polymerization, as well as a few examples showing the influence of the miktoarm structure on the morphology of block copolymers, are reviewed in this chapter.
Original language | English (US) |
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Title of host publication | Fluorinated Polymers, Volume 1 |
Subtitle of host publication | Synthesis, Properties, Processing and Simulation |
Editors | Ben Zhong Tang, Ashok Kakkar |
Publisher | Royal Society of Chemistry |
Pages | 1-30 |
Number of pages | 30 |
Edition | 25 |
ISBN (Electronic) | 9781782620341, 9781782624134, 9781782624158, 9781782625759, 9781782629160 |
DOIs | |
State | Published - 2017 |
Publication series
Name | RSC Polymer Chemistry Series |
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Number | 25 |
Volume | 2017-January |
ISSN (Print) | 2044-0790 |
ISSN (Electronic) | 2044-0804 |
Bibliographical note
Publisher Copyright:© The Royal Society of Chemistry 2017.
ASJC Scopus subject areas
- Bioengineering
- Polymers and Plastics
- Biotechnology
- Biomaterials