Abstract
An example for the catalytic synthesis of densely functionalized 1,2,3-triazoles through a LUMO activation mode has been developed. The protocol is enabled by intermolecular cross coupling reactions of azides with in situ-generated alpha,beta-unsaturated acyl azoliums. High yields and broad scope as well as the investigation of reaction mechanism are reported.
Original language | English (US) |
---|---|
Pages (from-to) | 2139-2144 |
Number of pages | 6 |
Journal | ACS Catalysis |
Volume | 7 |
Issue number | 3 |
DOIs | |
State | Published - Feb 20 2017 |
Bibliographical note
KAUST Repository Item: Exported on 2020-10-01Acknowledgements: Generous financial supports are provided by the National Natural Science Foundation of China (21672121, 21502043), the