Catalytic C1
 Alkylation with Methanol and Isotope-Labeled Methanol

Jan Sklyaruk; Jannik C. Borghs; Osama El-Sepelgy; Magnus Rueping

doi:10.1002/anie.201810885

Catalytic C1 Alkylation with Methanol and Isotope-Labeled Methanol

Jan Sklyaruk, Jannik C. Borghs, Osama El-Sepelgy, Magnus Rueping

Research output: Contribution to journal › Article › peer-review

111 Scopus citations

Abstract

A metal-catalyzed methylation process has been developed. By employing an air- and moisture-stable manganese catalyst together with isotopically labeled methanol, a series of D-, CD-, and C-labeled products were obtained in good yields under mild reaction conditions with water as the only byproduct.

Original language	English (US)
Pages (from-to)	775-779
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	58
Issue number	3
DOIs	https://doi.org/10.1002/anie.201810885 https://doi.org/10.1002/ange.201810885
State	Published - Dec 17 2018

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: J.S. is grateful for a doctoral fellowship provided by the Fonds der Chemischen Industrie. J.C.B. acknowledges the DBU for a doctoral fellowship.

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https://repository.kaust.edu.sa/bitstream/10754/631191/1/Manuscript%20revised.pdf

Cite this

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title = "Catalytic C1 Alkylation with Methanol and Isotope-Labeled Methanol",

abstract = "A metal-catalyzed methylation process has been developed. By employing an air- and moisture-stable manganese catalyst together with isotopically labeled methanol, a series of D-, CD-, and C-labeled products were obtained in good yields under mild reaction conditions with water as the only byproduct.",

author = "Jan Sklyaruk and Borghs, {Jannik C.} and Osama El-Sepelgy and Magnus Rueping",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: J.S. is grateful for a doctoral fellowship provided by the Fonds der Chemischen Industrie. J.C.B. acknowledges the DBU for a doctoral fellowship.",

year = "2018",

month = dec,

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doi = "10.1002/anie.201810885",

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T1 - Catalytic C1 Alkylation with Methanol and Isotope-Labeled Methanol

AU - Sklyaruk, Jan

AU - Borghs, Jannik C.

AU - El-Sepelgy, Osama

AU - Rueping, Magnus

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: J.S. is grateful for a doctoral fellowship provided by the Fonds der Chemischen Industrie. J.C.B. acknowledges the DBU for a doctoral fellowship.

PY - 2018/12/17

Y1 - 2018/12/17

N2 - A metal-catalyzed methylation process has been developed. By employing an air- and moisture-stable manganese catalyst together with isotopically labeled methanol, a series of D-, CD-, and C-labeled products were obtained in good yields under mild reaction conditions with water as the only byproduct.

AB - A metal-catalyzed methylation process has been developed. By employing an air- and moisture-stable manganese catalyst together with isotopically labeled methanol, a series of D-, CD-, and C-labeled products were obtained in good yields under mild reaction conditions with water as the only byproduct.

UR - http://hdl.handle.net/10754/631191

UR - https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201810885

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U2 - 10.1002/anie.201810885

DO - 10.1002/anie.201810885

M3 - Article

SN - 1433-7851

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JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 3

ER -

Catalytic C1 Alkylation with Methanol and Isotope-Labeled Methanol

Abstract

Bibliographical note

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