Carbonization of covalent triazine-based frameworks: Via ionic liquid induction

Jiangtao Jia, Zhijie Chen, Youssef Belmabkhout, Karim Adil, Prashant M. Bhatt, Vera A. Solovyeva, Osama Shekhah, Mohamed Eddaoudi*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

A series of porous organic polymers (POPs) were synthesized using tetrahedral 1,3,5,7-tetracyanoadamantane as the main building block. The POP frameworks in the presence of different amounts of molten ZnCl2 as an ionic liquid were allowed to alter/enhance the Brunauer-Emmett-Teller (BET) surface areas of the POPs in the range from 760 to 1560 m2 g-1. The mechanism of the carbonization was unveiled by IR, EA and solid-state NMR; which is in situ ionic liquid induced polymerization and carbonization of the POPs.

Original languageEnglish (US)
Pages (from-to)15564-15568
Number of pages5
JournalJournal of Materials Chemistry A
Volume6
Issue number32
DOIs
StatePublished - 2018

Bibliographical note

Publisher Copyright:
© 2018 The Royal Society of Chemistry.

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

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