Carbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Framework

Lin Huang; Ming Xue; Qingshan Song; Siru Chen; Ying Pan; Shilun Qiu

doi:10.1016/j.inoche.2014.04.026

Carbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Framework

Lin Huang, Ming Xue, Qingshan Song, Siru Chen, Ying Pan, Shilun Qiu

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A new mixed-ligand Zeolitic Imidazolate Framework Zn4(2-mbIm) 3(bIm)5·4H2O (named JUC-160, 2-mbIm = 2-methylbenzimidazole, bIm = benzimidazole and JUC = Jilin University China) was synthesized with a solvothermal reaction of Zn(NO3) 2·6H2O, bIm and 2-mbIm in DMF solution at 180 °C. Topological analysis indicated that JUC-160 has a zeolite GIS (gismondine) topology. Study of the gas adsorption and thermal and chemical stability of JUC-160 demonstrated its selective adsorption property for carbon dioxide, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvent for up to one week. © 2014 Elsevier B.V.

Original language	English (US)
Pages (from-to)	9-12
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	46
DOIs	https://doi.org/10.1016/j.inoche.2014.04.026
State	Published - Aug 2014
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009
Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21101072, 21261130584, 91022030), "111" project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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title = "Carbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Framework",

abstract = "A new mixed-ligand Zeolitic Imidazolate Framework Zn4(2-mbIm) 3(bIm)5·4H2O (named JUC-160, 2-mbIm = 2-methylbenzimidazole, bIm = benzimidazole and JUC = Jilin University China) was synthesized with a solvothermal reaction of Zn(NO3) 2·6H2O, bIm and 2-mbIm in DMF solution at 180 °C. Topological analysis indicated that JUC-160 has a zeolite GIS (gismondine) topology. Study of the gas adsorption and thermal and chemical stability of JUC-160 demonstrated its selective adsorption property for carbon dioxide, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvent for up to one week. {\textcopyright} 2014 Elsevier B.V.",

author = "Lin Huang and Ming Xue and Qingshan Song and Siru Chen and Ying Pan and Shilun Qiu",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21101072, 21261130584, 91022030), {"}111{"} project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009). This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2014",

month = aug,

doi = "10.1016/j.inoche.2014.04.026",

language = "English (US)",

volume = "46",

pages = "9--12",

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T1 - Carbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Framework

AU - Huang, Lin

AU - Xue, Ming

AU - Song, Qingshan

AU - Chen, Siru

AU - Pan, Ying

AU - Qiu, Shilun

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21101072, 21261130584, 91022030), "111" project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009). This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2014/8

Y1 - 2014/8

N2 - A new mixed-ligand Zeolitic Imidazolate Framework Zn4(2-mbIm) 3(bIm)5·4H2O (named JUC-160, 2-mbIm = 2-methylbenzimidazole, bIm = benzimidazole and JUC = Jilin University China) was synthesized with a solvothermal reaction of Zn(NO3) 2·6H2O, bIm and 2-mbIm in DMF solution at 180 °C. Topological analysis indicated that JUC-160 has a zeolite GIS (gismondine) topology. Study of the gas adsorption and thermal and chemical stability of JUC-160 demonstrated its selective adsorption property for carbon dioxide, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvent for up to one week. © 2014 Elsevier B.V.

AB - A new mixed-ligand Zeolitic Imidazolate Framework Zn4(2-mbIm) 3(bIm)5·4H2O (named JUC-160, 2-mbIm = 2-methylbenzimidazole, bIm = benzimidazole and JUC = Jilin University China) was synthesized with a solvothermal reaction of Zn(NO3) 2·6H2O, bIm and 2-mbIm in DMF solution at 180 °C. Topological analysis indicated that JUC-160 has a zeolite GIS (gismondine) topology. Study of the gas adsorption and thermal and chemical stability of JUC-160 demonstrated its selective adsorption property for carbon dioxide, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvent for up to one week. © 2014 Elsevier B.V.

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U2 - 10.1016/j.inoche.2014.04.026

DO - 10.1016/j.inoche.2014.04.026

M3 - Article

SN - 1387-7003

VL - 46

SP - 9

EP - 12

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Carbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Framework

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