Ca2+ and Mg2+ incorporated barium hexaferrites: structural and magnetic properties

M. A. Almessiere; Y. Slimani; H. S. El Sayed; A. Baykal

doi:10.1007/s10971-018-4853-1

Ca2+ and Mg2+ incorporated barium hexaferrites: structural and magnetic properties

M. A. Almessiere, Y. Slimani, H. S. El Sayed, A. Baykal

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

BaM hexaferrites substituted with both Ca2+ and Mg2+ ions, namely, Ba1-2×CaxMgxFe12O19 (0.0 ≤ x ≤ 0.1), synthesized during a sol–gel auto-combustion route. The hexaferrite phase and morphology of all samples were investigated using X-ray powder diffraction, a field emission scanning electron microscope, a high-resolution transmission microscope, and Fourier transform infrared spectroscopy. In addition, an M-type hexagonal structure was confirmed using XRD for all samples. FE-SEM and TEM revealed the shape of the hexagonal plate. Measurements of the magnetization versus the field M(H) of Ba1-2×CaxMgxFe12O19 (0.0 ≤ x ≤ 0.1) nanohexaferrites were conducted at 300 and 10 K. A hard-ferrimagnetic behavior at both 300 and 10 K was noted for the different products produced. The squareness ratio indicates the uniaxial anisotropy for various products. The deduced values of saturation magnetization (Ms) in all substituted samples are higher than in the pristine sample (x = 0). The Ba0.96Ca0.02Mg0.02Fe12O19 nanosized hexaferrite showed the highest values of Ms, remanence Mr, magneton number (nB), and magnetocrystalline anisotropy constant (Keff). In contrast, the values of the coercive field (Hc) and intrinsic coercivity (Hci) diminish with the increase in the amount of the substituted Ca and Mg elements.

Original language	English (US)
Pages (from-to)	628-638
Number of pages	11
Journal	Journal of Sol-Gel Science and Technology
Volume	88
Issue number	3
DOIs	https://doi.org/10.1007/s10971-018-4853-1
State	Published - Nov 5 2018
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2022-06-07
Acknowledgements: The authors would like to thank the Deanship of Scientific Research (DSR) and the Institute for Research & Medical Consultations (IRMC) of Imam Abdulrahman Bin Faisal University for providing financial assistance to this study (Application No, 2017-605-IRMC) and Core Labs of King Abdullah University of Science and Technology (KAUST) for the use of their resources.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

ASJC Scopus subject areas

Materials Chemistry
Biomaterials
Ceramics and Composites
General Chemistry
Electronic, Optical and Magnetic Materials
Condensed Matter Physics

Access to Document

10.1007/s10971-018-4853-1

Cite this

@article{dfab6dabae0b44dea15420c73a6fa973,

title = "Ca2+ and Mg2+ incorporated barium hexaferrites: structural and magnetic properties",

abstract = "BaM hexaferrites substituted with both Ca2+ and Mg2+ ions, namely, Ba1-2×CaxMgxFe12O19 (0.0 ≤ x ≤ 0.1), synthesized during a sol–gel auto-combustion route. The hexaferrite phase and morphology of all samples were investigated using X-ray powder diffraction, a field emission scanning electron microscope, a high-resolution transmission microscope, and Fourier transform infrared spectroscopy. In addition, an M-type hexagonal structure was confirmed using XRD for all samples. FE-SEM and TEM revealed the shape of the hexagonal plate. Measurements of the magnetization versus the field M(H) of Ba1-2×CaxMgxFe12O19 (0.0 ≤ x ≤ 0.1) nanohexaferrites were conducted at 300 and 10 K. A hard-ferrimagnetic behavior at both 300 and 10 K was noted for the different products produced. The squareness ratio indicates the uniaxial anisotropy for various products. The deduced values of saturation magnetization (Ms) in all substituted samples are higher than in the pristine sample (x = 0). The Ba0.96Ca0.02Mg0.02Fe12O19 nanosized hexaferrite showed the highest values of Ms, remanence Mr, magneton number (nB), and magnetocrystalline anisotropy constant (Keff). In contrast, the values of the coercive field (Hc) and intrinsic coercivity (Hci) diminish with the increase in the amount of the substituted Ca and Mg elements.",

author = "Almessiere, {M. A.} and Y. Slimani and {El Sayed}, {H. S.} and A. Baykal",

note = "KAUST Repository Item: Exported on 2022-06-07 Acknowledgements: The authors would like to thank the Deanship of Scientific Research (DSR) and the Institute for Research & Medical Consultations (IRMC) of Imam Abdulrahman Bin Faisal University for providing financial assistance to this study (Application No, 2017-605-IRMC) and Core Labs of King Abdullah University of Science and Technology (KAUST) for the use of their resources. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2018",

month = nov,

day = "5",

doi = "10.1007/s10971-018-4853-1",

language = "English (US)",

volume = "88",

pages = "628--638",

journal = "Journal of Sol-Gel Science and Technology",

issn = "1573-4846",

publisher = "Springer Netherlands",

number = "3",

}

TY - JOUR

T1 - Ca2+ and Mg2+ incorporated barium hexaferrites: structural and magnetic properties

AU - Almessiere, M. A.

AU - Slimani, Y.

AU - El Sayed, H. S.

AU - Baykal, A.

N1 - KAUST Repository Item: Exported on 2022-06-07 Acknowledgements: The authors would like to thank the Deanship of Scientific Research (DSR) and the Institute for Research & Medical Consultations (IRMC) of Imam Abdulrahman Bin Faisal University for providing financial assistance to this study (Application No, 2017-605-IRMC) and Core Labs of King Abdullah University of Science and Technology (KAUST) for the use of their resources. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2018/11/5

Y1 - 2018/11/5

N2 - BaM hexaferrites substituted with both Ca2+ and Mg2+ ions, namely, Ba1-2×CaxMgxFe12O19 (0.0 ≤ x ≤ 0.1), synthesized during a sol–gel auto-combustion route. The hexaferrite phase and morphology of all samples were investigated using X-ray powder diffraction, a field emission scanning electron microscope, a high-resolution transmission microscope, and Fourier transform infrared spectroscopy. In addition, an M-type hexagonal structure was confirmed using XRD for all samples. FE-SEM and TEM revealed the shape of the hexagonal plate. Measurements of the magnetization versus the field M(H) of Ba1-2×CaxMgxFe12O19 (0.0 ≤ x ≤ 0.1) nanohexaferrites were conducted at 300 and 10 K. A hard-ferrimagnetic behavior at both 300 and 10 K was noted for the different products produced. The squareness ratio indicates the uniaxial anisotropy for various products. The deduced values of saturation magnetization (Ms) in all substituted samples are higher than in the pristine sample (x = 0). The Ba0.96Ca0.02Mg0.02Fe12O19 nanosized hexaferrite showed the highest values of Ms, remanence Mr, magneton number (nB), and magnetocrystalline anisotropy constant (Keff). In contrast, the values of the coercive field (Hc) and intrinsic coercivity (Hci) diminish with the increase in the amount of the substituted Ca and Mg elements.

AB - BaM hexaferrites substituted with both Ca2+ and Mg2+ ions, namely, Ba1-2×CaxMgxFe12O19 (0.0 ≤ x ≤ 0.1), synthesized during a sol–gel auto-combustion route. The hexaferrite phase and morphology of all samples were investigated using X-ray powder diffraction, a field emission scanning electron microscope, a high-resolution transmission microscope, and Fourier transform infrared spectroscopy. In addition, an M-type hexagonal structure was confirmed using XRD for all samples. FE-SEM and TEM revealed the shape of the hexagonal plate. Measurements of the magnetization versus the field M(H) of Ba1-2×CaxMgxFe12O19 (0.0 ≤ x ≤ 0.1) nanohexaferrites were conducted at 300 and 10 K. A hard-ferrimagnetic behavior at both 300 and 10 K was noted for the different products produced. The squareness ratio indicates the uniaxial anisotropy for various products. The deduced values of saturation magnetization (Ms) in all substituted samples are higher than in the pristine sample (x = 0). The Ba0.96Ca0.02Mg0.02Fe12O19 nanosized hexaferrite showed the highest values of Ms, remanence Mr, magneton number (nB), and magnetocrystalline anisotropy constant (Keff). In contrast, the values of the coercive field (Hc) and intrinsic coercivity (Hci) diminish with the increase in the amount of the substituted Ca and Mg elements.

UR - http://hdl.handle.net/10754/678636

UR - http://link.springer.com/10.1007/s10971-018-4853-1

UR - http://www.scopus.com/inward/record.url?scp=85056272934&partnerID=8YFLogxK

U2 - 10.1007/s10971-018-4853-1

DO - 10.1007/s10971-018-4853-1

M3 - Article

SN - 1573-4846

VL - 88

SP - 628

EP - 638

JO - Journal of Sol-Gel Science and Technology

JF - Journal of Sol-Gel Science and Technology

IS - 3

ER -

Ca2+ and Mg2+ incorporated barium hexaferrites: structural and magnetic properties

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this