C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex

Kuo-Wei Huang; Yuan Wang; Bin Zheng; Yupeng Pan; Chengling Pan; Lipeng He

doi:10.1039/C5DT00787A

C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex

Kuo-Wei Huang, Yuan Wang, Bin Zheng, Yupeng Pan, Chengling Pan, Lipeng He

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33 Scopus citations

Abstract

A neutral complex PN3P-Rh(I)Cl (2) was prepared from a reaction of the PN3P pincer ligand (1) with [Rh(COD)Cl]2 (COD = 1,5-cyclooctadiene). Upon treatment with a suitable base, H–H and Csp2–H activation reactions can be achieved through the deprotonation/reprotonation of one of the N–H arms and dearomatization/rearomatization of the central pyridine ring with the oxidation state of Rh remaining I.

Original language	English (US)
Pages (from-to)	15111-15115
Number of pages	5
Journal	Dalton Trans.
Volume	44
Issue number	34
DOIs	https://doi.org/10.1039/C5DT00787A
State	Published - 2015

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title = "C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex",

abstract = "A neutral complex PN3P-Rh(I)Cl (2) was prepared from a reaction of the PN3P pincer ligand (1) with [Rh(COD)Cl]2 (COD = 1,5-cyclooctadiene). Upon treatment with a suitable base, H–H and Csp2–H activation reactions can be achieved through the deprotonation/reprotonation of one of the N–H arms and dearomatization/rearomatization of the central pyridine ring with the oxidation state of Rh remaining I.",

author = "Kuo-Wei Huang and Yuan Wang and Bin Zheng and Yupeng Pan and Chengling Pan and Lipeng He",

note = "KAUST Repository Item: Exported on 2020-10-01",

year = "2015",

doi = "10.1039/C5DT00787A",

language = "English (US)",

volume = "44",

pages = "15111--15115",

journal = "Dalton Trans.",

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T1 - C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex

AU - Huang, Kuo-Wei

AU - Wang, Yuan

AU - Zheng, Bin

AU - Pan, Yupeng

AU - Pan, Chengling

AU - He, Lipeng

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2015

Y1 - 2015

N2 - A neutral complex PN3P-Rh(I)Cl (2) was prepared from a reaction of the PN3P pincer ligand (1) with [Rh(COD)Cl]2 (COD = 1,5-cyclooctadiene). Upon treatment with a suitable base, H–H and Csp2–H activation reactions can be achieved through the deprotonation/reprotonation of one of the N–H arms and dearomatization/rearomatization of the central pyridine ring with the oxidation state of Rh remaining I.

AB - A neutral complex PN3P-Rh(I)Cl (2) was prepared from a reaction of the PN3P pincer ligand (1) with [Rh(COD)Cl]2 (COD = 1,5-cyclooctadiene). Upon treatment with a suitable base, H–H and Csp2–H activation reactions can be achieved through the deprotonation/reprotonation of one of the N–H arms and dearomatization/rearomatization of the central pyridine ring with the oxidation state of Rh remaining I.

UR - http://hdl.handle.net/10754/550320

UR - http://pubs.rsc.org/en/Content/ArticleLanding/2015/DT/C5DT00787A

UR - http://www.scopus.com/inward/record.url?scp=84939618351&partnerID=8YFLogxK

U2 - 10.1039/C5DT00787A

DO - 10.1039/C5DT00787A

M3 - Article

C2 - 25893483

SN - 1477-9226

VL - 44

SP - 15111

EP - 15115

JO - Dalton Trans.

JF - Dalton Trans.

IS - 34

ER -

C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex

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CCDC 1050932: Experimental Crystal Structure Determination : Carbonyl-(N,N'-(pyridin-2-yl-6-ylidene)bis(P,P-di-t-butyl(phosphinous amidato)))-rhodium

CCDC 1050930: Experimental Crystal Structure Determination : Chloro-(N,N'-(pyridine-2,6-diyl)bis(P,P-di-t-butyl(phosphinous amide)))-rhodium tetrahydrofuran solvate

CCDC 1050933: Experimental Crystal Structure Determination : Carbonyl-(N,N'-(pyridine-2,6-diyl)bis(P,P-di-t-butyl(phosphinous amide)))-rhodium formate formic acid solvate

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C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex

Abstract

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Access to Document

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Datasets

CCDC 1050932: Experimental Crystal Structure Determination : Carbonyl-(N,N'-(pyridin-2-yl-6-ylidene)bis(P,P-di-t-butyl(phosphinous amidato)))-rhodium

CCDC 1050930: Experimental Crystal Structure Determination : Chloro-(N,N'-(pyridine-2,6-diyl)bis(P,P-di-t-butyl(phosphinous amide)))-rhodium tetrahydrofuran solvate

CCDC 1050933: Experimental Crystal Structure Determination : Carbonyl-(N,N'-(pyridine-2,6-diyl)bis(P,P-di-t-butyl(phosphinous amide)))-rhodium formate formic acid solvate

Cite this