Bulk and Interfacial Properties of Brine or Alkane in the Presence of Carbon Dioxide, Methane, and Their Mixture

Arun Kumar Narayanan Nair*, Mohd Fuad Anwari Che Ruslan, Marcia Luna Ramirez Hincapie, Shuyu Sun*

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

7 Scopus citations

Abstract

We present an overview of the molecular simulations performed to understand the two-phase behavior of brine or alkane in the presence of CH4, CO2, and their mixture at reservoir conditions. The simulation results of bulk and interfacial properties of these systems compared well with experimental data and theoretical estimates obtained using, for example, density gradient theory based on CPA (with Debye-Hückel electrostatic term) and PC-SAFT EoSs. Here, CO2is preferentially dissolved in the water-rich or alkane-rich phase and enriched at the interface from the CH4/CO2equimolar mixture. The fact that the interfacial enrichment in CO2was much higher than that of CH4explained the relatively steep decrease in the interfacial tension (IFT) with pressure in brine+CO2and alkane+CO2systems. IFTs of brine+CH4+CO2and alkane+CH4+CO2systems decreased with increasing mole fraction of CO2in the CH4/CO2-rich phase. Solubilities of CH4and CO2in the water-rich phase decreased with the addition of salt (salting-out effect). This effect followed the order NaCl < CaCl2. IFTs of brine+CH4/CO2systems linearly increased as the salt concentration increased. Here, the larger slopes in the presence of CaCl2are due to stronger hydration and repulsion from the interface of Ca2+ions. Solubilities of CH4and CO2in the alkane-rich phase generally decreased with increasing alkane size nc. These solubilities were relatively lower in the cycloalkane-rich phase, while linear and branched alkanes gave similar results. IFTs of alkane+CH4/CO2systems increased as ncincreased and a relatively high IFT was obtained in cycloalkane+CH4/CO2systems.

Original languageEnglish (US)
Pages (from-to)5016-5029
Number of pages14
JournalIndustrial and Engineering Chemistry Research
Volume61
Issue number15
DOIs
StatePublished - Apr 20 2022

Bibliographical note

Funding Information:
This study was supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No. OSR-2019-CRG8-4074. We also acknowledge computational facilities provided by KAUST.

Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.

ASJC Scopus subject areas

  • General Chemistry
  • General Chemical Engineering
  • Industrial and Manufacturing Engineering

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