TY - JOUR
T1 - Boron-Catalyzed C3-Polymerization of ω-2-Methyl Allylarsonium Ylide and Its C3/C1 Copolymers with Dimethylsulfoxonium Methylide
AU - Wang, De
AU - Zhang, Zhen
AU - Hadjichristidis, Nikos
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Research reported in this publication was supported by the King Abdullah University of Science and Technology.
PY - 2016/3
Y1 - 2016/3
N2 - A novel arsonium ylide, ω-2-methylallylarsonium ylide, was synthesized and used as monomer for polyhomologation with triethyborane as initiator. It was found that the terminal methyl group leads to C3 polymerization. Furthermore, the copolyhomologation of arsonium ylide with dimethylsulfoxonium methylide is reported for the first time. (Chemical Equation Presented). © 2016 American Chemical Society.
AB - A novel arsonium ylide, ω-2-methylallylarsonium ylide, was synthesized and used as monomer for polyhomologation with triethyborane as initiator. It was found that the terminal methyl group leads to C3 polymerization. Furthermore, the copolyhomologation of arsonium ylide with dimethylsulfoxonium methylide is reported for the first time. (Chemical Equation Presented). © 2016 American Chemical Society.
UR - http://hdl.handle.net/10754/621694
UR - http://pubs.acs.org/doi/abs/10.1021/acsmacrolett.6b00082
UR - http://www.scopus.com/inward/record.url?scp=84961783974&partnerID=8YFLogxK
U2 - 10.1021/acsmacrolett.6b00082
DO - 10.1021/acsmacrolett.6b00082
M3 - Article
SN - 2161-1653
VL - 5
SP - 387
EP - 390
JO - ACS Macro Letters
JF - ACS Macro Letters
IS - 3
ER -