Block copolymer directed synthesis of mesoporous TiO 2 for dye-sensitized solar cells

Mihaela Nedelcu; Jinwoo Lee; Edward J. W. Crossland; Scott C. Warren; M. Christopher Orilall; Stefan Guldin; Sven Hüttner; Catarina Ducati; Dominik Eder; Ulrich Wiesner; Ullrich Steiner; Henry J. Snaith

doi:10.1039/b815166k

Block copolymer directed synthesis of mesoporous TiO 2 for dye-sensitized solar cells

Mihaela Nedelcu, Jinwoo Lee, Edward J. W. Crossland, Scott C. Warren, M. Christopher Orilall, Stefan Guldin, Sven Hüttner, Catarina Ducati, Dominik Eder, Ulrich Wiesner, Ullrich Steiner, Henry J. Snaith

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103 Scopus citations

Abstract

The morphology of TiO2 plays an important role in the operation of solid-state dye-sensitized solar cells. By using polyisoprene-block- ethyleneoxide (PI-b-PEO) copolymers as structure directing agents for a sol-gel based synthesis of mesoporous TiO2, we demonstrate a strategy for the detailed control of the semiconductor morphology on the 10 nm length scale. The careful adjustment of polymer molecular weight and titania precursor content is used to systematically vary the material structure and its influence upon solar cell performance is investigated. Furthermore, the use of a partially sp 2 hybridized structure directing polymer enables the crystallization of porous TiO2 networks at high temperatures without pore collapse, improving its performance in solid-state dye-sensitized solar cells. © 2009 The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	134-139
Number of pages	6
Journal	Soft Matter
Volume	5
Issue number	1
DOIs	https://doi.org/10.1039/b815166k
State	Published - 2009

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: M. N., S. H., and U. S. acknowledge financial support from the European network "PolyFilm" under RTN-6. This work was in part funded by EPSRC, NSF (DMR-0404195) and KAUST. The sabbatical leave of U. W. was supported by the Leverhulme Trust and EPSRC. C. D. acknowledges the Royal Society for Funding. We thank Richard Friend for support.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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@article{c7382f7638a44437bf0ca1e20e761402,

title = "Block copolymer directed synthesis of mesoporous TiO 2 for dye-sensitized solar cells",

abstract = "The morphology of TiO2 plays an important role in the operation of solid-state dye-sensitized solar cells. By using polyisoprene-block- ethyleneoxide (PI-b-PEO) copolymers as structure directing agents for a sol-gel based synthesis of mesoporous TiO2, we demonstrate a strategy for the detailed control of the semiconductor morphology on the 10 nm length scale. The careful adjustment of polymer molecular weight and titania precursor content is used to systematically vary the material structure and its influence upon solar cell performance is investigated. Furthermore, the use of a partially sp 2 hybridized structure directing polymer enables the crystallization of porous TiO2 networks at high temperatures without pore collapse, improving its performance in solid-state dye-sensitized solar cells. {\textcopyright} 2009 The Royal Society of Chemistry.",

author = "Mihaela Nedelcu and Jinwoo Lee and Crossland, {Edward J. W.} and Warren, {Scott C.} and Orilall, {M. Christopher} and Stefan Guldin and Sven H{\"u}ttner and Catarina Ducati and Dominik Eder and Ulrich Wiesner and Ullrich Steiner and Snaith, {Henry J.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: M. N., S. H., and U. S. acknowledge financial support from the European network {"}PolyFilm{"} under RTN-6. This work was in part funded by EPSRC, NSF (DMR-0404195) and KAUST. The sabbatical leave of U. W. was supported by the Leverhulme Trust and EPSRC. C. D. acknowledges the Royal Society for Funding. We thank Richard Friend for support. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2009",

doi = "10.1039/b815166k",

language = "English (US)",

volume = "5",

pages = "134--139",

journal = "Soft Matter",

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publisher = "Royal Society of Chemistry",

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T1 - Block copolymer directed synthesis of mesoporous TiO 2 for dye-sensitized solar cells

AU - Nedelcu, Mihaela

AU - Lee, Jinwoo

AU - Crossland, Edward J. W.

AU - Warren, Scott C.

AU - Orilall, M. Christopher

AU - Guldin, Stefan

AU - Hüttner, Sven

AU - Ducati, Catarina

AU - Eder, Dominik

AU - Wiesner, Ulrich

AU - Steiner, Ullrich

AU - Snaith, Henry J.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: M. N., S. H., and U. S. acknowledge financial support from the European network "PolyFilm" under RTN-6. This work was in part funded by EPSRC, NSF (DMR-0404195) and KAUST. The sabbatical leave of U. W. was supported by the Leverhulme Trust and EPSRC. C. D. acknowledges the Royal Society for Funding. We thank Richard Friend for support. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2009

Y1 - 2009

N2 - The morphology of TiO2 plays an important role in the operation of solid-state dye-sensitized solar cells. By using polyisoprene-block- ethyleneoxide (PI-b-PEO) copolymers as structure directing agents for a sol-gel based synthesis of mesoporous TiO2, we demonstrate a strategy for the detailed control of the semiconductor morphology on the 10 nm length scale. The careful adjustment of polymer molecular weight and titania precursor content is used to systematically vary the material structure and its influence upon solar cell performance is investigated. Furthermore, the use of a partially sp 2 hybridized structure directing polymer enables the crystallization of porous TiO2 networks at high temperatures without pore collapse, improving its performance in solid-state dye-sensitized solar cells. © 2009 The Royal Society of Chemistry.

AB - The morphology of TiO2 plays an important role in the operation of solid-state dye-sensitized solar cells. By using polyisoprene-block- ethyleneoxide (PI-b-PEO) copolymers as structure directing agents for a sol-gel based synthesis of mesoporous TiO2, we demonstrate a strategy for the detailed control of the semiconductor morphology on the 10 nm length scale. The careful adjustment of polymer molecular weight and titania precursor content is used to systematically vary the material structure and its influence upon solar cell performance is investigated. Furthermore, the use of a partially sp 2 hybridized structure directing polymer enables the crystallization of porous TiO2 networks at high temperatures without pore collapse, improving its performance in solid-state dye-sensitized solar cells. © 2009 The Royal Society of Chemistry.

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DO - 10.1039/b815166k

M3 - Article

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SP - 134

EP - 139

JO - Soft Matter

JF - Soft Matter

IS - 1

ER -

Block copolymer directed synthesis of mesoporous TiO 2 for dye-sensitized solar cells

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