Bi-functional modified-phosphate catalyzed the synthesis of α-α′-(EE)-bis(benzylidene)-cycloalkanones: Microwave versus conventional-heating

Abderrahim Solhy; Walid Amer; Mohammed Karkouri; Rachid Tahir; Abdeslam El Bouari; Aziz Fihri; Mostapha M. Bousmina; Mohamed Zahouily

doi:10.1016/j.molcata.2010.11.032

Bi-functional modified-phosphate catalyzed the synthesis of α-α′-(EE)-bis(benzylidene)-cycloalkanones: Microwave versus conventional-heating

Abderrahim Solhy, Walid Amer, Mohammed Karkouri, Rachid Tahir, Abdeslam El Bouari, Aziz Fihri, Mostapha M. Bousmina, Mohamed Zahouily

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The impregnation of hydroxyapatite (HAP) by NaNO3 leads to a modified-hydroxyapatite which has a bi-functional acid-base property. Sodium-modified-hydroxyapatite (Na-HAP) efficiently catalyzed the cross-aldol condensation of arylaldehydes and cycloketones to afford α-α′- (EE)-bis(benzylidene)-cycloalkanones in good yields under microwave irradiation. Moreover, the methodology described in this paper provides a very easy and efficient synthesis carried out in water as the greenest available solvent under conventional heating. A comparison study between these two different modes of heating was investigated. The catalyst was easily recovered and efficiently re-used. © 2010 Elsevier B.V.

Original language	English (US)
Pages (from-to)	8-15
Number of pages	8
Journal	Journal of Molecular Catalysis A: Chemical
Volume	336
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2010.11.032
State	Published - Feb 2011

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Thanks are due to Hassan II Academy of Science and Technology and Centre National de la Recherche Scientifique et Technique (CNRST), for their financial support.

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Process Chemistry and Technology

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10.1016/j.molcata.2010.11.032

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title = "Bi-functional modified-phosphate catalyzed the synthesis of α-α′-(EE)-bis(benzylidene)-cycloalkanones: Microwave versus conventional-heating",

abstract = "The impregnation of hydroxyapatite (HAP) by NaNO3 leads to a modified-hydroxyapatite which has a bi-functional acid-base property. Sodium-modified-hydroxyapatite (Na-HAP) efficiently catalyzed the cross-aldol condensation of arylaldehydes and cycloketones to afford α-α′- (EE)-bis(benzylidene)-cycloalkanones in good yields under microwave irradiation. Moreover, the methodology described in this paper provides a very easy and efficient synthesis carried out in water as the greenest available solvent under conventional heating. A comparison study between these two different modes of heating was investigated. The catalyst was easily recovered and efficiently re-used. {\textcopyright} 2010 Elsevier B.V.",

author = "Abderrahim Solhy and Walid Amer and Mohammed Karkouri and Rachid Tahir and {El Bouari}, Abdeslam and Aziz Fihri and Bousmina, {Mostapha M.} and Mohamed Zahouily",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Thanks are due to Hassan II Academy of Science and Technology and Centre National de la Recherche Scientifique et Technique (CNRST), for their financial support.",

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doi = "10.1016/j.molcata.2010.11.032",

language = "English (US)",

volume = "336",

pages = "8--15",

journal = "Journal of Molecular Catalysis A: Chemical",

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T1 - Bi-functional modified-phosphate catalyzed the synthesis of α-α′-(EE)-bis(benzylidene)-cycloalkanones: Microwave versus conventional-heating

AU - Solhy, Abderrahim

AU - Amer, Walid

AU - Karkouri, Mohammed

AU - Tahir, Rachid

AU - El Bouari, Abdeslam

AU - Fihri, Aziz

AU - Bousmina, Mostapha M.

AU - Zahouily, Mohamed

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Thanks are due to Hassan II Academy of Science and Technology and Centre National de la Recherche Scientifique et Technique (CNRST), for their financial support.

PY - 2011/2

Y1 - 2011/2

N2 - The impregnation of hydroxyapatite (HAP) by NaNO3 leads to a modified-hydroxyapatite which has a bi-functional acid-base property. Sodium-modified-hydroxyapatite (Na-HAP) efficiently catalyzed the cross-aldol condensation of arylaldehydes and cycloketones to afford α-α′- (EE)-bis(benzylidene)-cycloalkanones in good yields under microwave irradiation. Moreover, the methodology described in this paper provides a very easy and efficient synthesis carried out in water as the greenest available solvent under conventional heating. A comparison study between these two different modes of heating was investigated. The catalyst was easily recovered and efficiently re-used. © 2010 Elsevier B.V.

AB - The impregnation of hydroxyapatite (HAP) by NaNO3 leads to a modified-hydroxyapatite which has a bi-functional acid-base property. Sodium-modified-hydroxyapatite (Na-HAP) efficiently catalyzed the cross-aldol condensation of arylaldehydes and cycloketones to afford α-α′- (EE)-bis(benzylidene)-cycloalkanones in good yields under microwave irradiation. Moreover, the methodology described in this paper provides a very easy and efficient synthesis carried out in water as the greenest available solvent under conventional heating. A comparison study between these two different modes of heating was investigated. The catalyst was easily recovered and efficiently re-used. © 2010 Elsevier B.V.

UR - http://hdl.handle.net/10754/561710

UR - https://linkinghub.elsevier.com/retrieve/pii/S1381116910005005

UR - http://www.scopus.com/inward/record.url?scp=79951681149&partnerID=8YFLogxK

U2 - 10.1016/j.molcata.2010.11.032

DO - 10.1016/j.molcata.2010.11.032

M3 - Article

SN - 1381-1169

VL - 336

SP - 8

EP - 15

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Bi-functional modified-phosphate catalyzed the synthesis of α-α′-(EE)-bis(benzylidene)-cycloalkanones: Microwave versus conventional-heating

Abstract

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