Benzocarborano[2,1- b:3,4- b ′]dithiophene containing conjugated polymers: Synthesis, characterization, and optoelectronic properties

Jonathan Marshall; Bob C. Schroeder; Hugo Bronstein; Iain Meager; Stephan Rossbauer; Nir Yaacobi-Gross; Ester Buchaca-Domingo; Thomas D. Anthopoulos; Natalie Stingelin; Peter Beavis; Martin Heeney

doi:10.1021/ma402273w

Benzocarborano[2,1- b:3,4- b ′]dithiophene containing conjugated polymers: Synthesis, characterization, and optoelectronic properties

Jonathan Marshall, Bob C. Schroeder, Hugo Bronstein, Iain Meager, Stephan Rossbauer, Nir Yaacobi-Gross, Ester Buchaca-Domingo, Thomas D. Anthopoulos, Natalie Stingelin, Peter Beavis, Martin Heeney

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20 Scopus citations

Abstract

We report the stannylation of a benzocarborano[2,1-b:3,4-b′] dithiophene monomer and its polymerization by Stille polycondensation with solubilized cyclopentadithiophene and diketopyrrolopyrrole derivatives. The physical, material, and optoelectronic properties of the resultant conjugated copolymers are reported, demonstrating that benzocarboranodithiophene acts as a mildly electron-withdrawing monomer. © 2013 American Chemical Society.

Original language	English (US)
Pages (from-to)	89-96
Number of pages	8
Journal	Macromolecules
Volume	47
Issue number	1
DOIs	https://doi.org/10.1021/ma402273w
State	Published - Jan 14 2014
Externally published	Yes

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Generated from Scopus record by KAUST IRTS on 2023-02-14

ASJC Scopus subject areas

Materials Chemistry
Organic Chemistry
Polymers and Plastics
Inorganic Chemistry

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10.1021/ma402273w

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Marshall, J., Schroeder, B. C., Bronstein, H., Meager, I., Rossbauer, S., Yaacobi-Gross, N., Buchaca-Domingo, E., Anthopoulos, T. D., Stingelin, N., Beavis, P., & Heeney, M. (2014). Benzocarborano[2,1- b:3,4- b ′]dithiophene containing conjugated polymers: Synthesis, characterization, and optoelectronic properties. Macromolecules, 47(1), 89-96. https://doi.org/10.1021/ma402273w

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abstract = "We report the stannylation of a benzocarborano[2,1-b:3,4-b′] dithiophene monomer and its polymerization by Stille polycondensation with solubilized cyclopentadithiophene and diketopyrrolopyrrole derivatives. The physical, material, and optoelectronic properties of the resultant conjugated copolymers are reported, demonstrating that benzocarboranodithiophene acts as a mildly electron-withdrawing monomer. {\textcopyright} 2013 American Chemical Society.",

author = "Jonathan Marshall and Schroeder, {Bob C.} and Hugo Bronstein and Iain Meager and Stephan Rossbauer and Nir Yaacobi-Gross and Ester Buchaca-Domingo and Anthopoulos, {Thomas D.} and Natalie Stingelin and Peter Beavis and Martin Heeney",

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doi = "10.1021/ma402273w",

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Marshall, J, Schroeder, BC, Bronstein, H, Meager, I, Rossbauer, S, Yaacobi-Gross, N, Buchaca-Domingo, E, Anthopoulos, TD, Stingelin, N, Beavis, P & Heeney, M 2014, 'Benzocarborano[2,1- b:3,4- b ′]dithiophene containing conjugated polymers: Synthesis, characterization, and optoelectronic properties', Macromolecules, vol. 47, no. 1, pp. 89-96. https://doi.org/10.1021/ma402273w

TY - JOUR

T1 - Benzocarborano[2,1- b:3,4- b ′]dithiophene containing conjugated polymers: Synthesis, characterization, and optoelectronic properties

AU - Marshall, Jonathan

AU - Schroeder, Bob C.

AU - Bronstein, Hugo

AU - Meager, Iain

AU - Rossbauer, Stephan

AU - Yaacobi-Gross, Nir

AU - Buchaca-Domingo, Ester

AU - Anthopoulos, Thomas D.

AU - Stingelin, Natalie

AU - Beavis, Peter

AU - Heeney, Martin

N1 - Generated from Scopus record by KAUST IRTS on 2023-02-14

PY - 2014/1/14

Y1 - 2014/1/14

N2 - We report the stannylation of a benzocarborano[2,1-b:3,4-b′] dithiophene monomer and its polymerization by Stille polycondensation with solubilized cyclopentadithiophene and diketopyrrolopyrrole derivatives. The physical, material, and optoelectronic properties of the resultant conjugated copolymers are reported, demonstrating that benzocarboranodithiophene acts as a mildly electron-withdrawing monomer. © 2013 American Chemical Society.

AB - We report the stannylation of a benzocarborano[2,1-b:3,4-b′] dithiophene monomer and its polymerization by Stille polycondensation with solubilized cyclopentadithiophene and diketopyrrolopyrrole derivatives. The physical, material, and optoelectronic properties of the resultant conjugated copolymers are reported, demonstrating that benzocarboranodithiophene acts as a mildly electron-withdrawing monomer. © 2013 American Chemical Society.

UR - https://pubs.acs.org/doi/10.1021/ma402273w

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U2 - 10.1021/ma402273w

DO - 10.1021/ma402273w

M3 - Article

SN - 0024-9297

VL - 47

SP - 89

EP - 96

JO - Macromolecules

JF - Macromolecules

IS - 1

ER -

Benzocarborano[2,1- b:3,4- b ′]dithiophene containing conjugated polymers: Synthesis, characterization, and optoelectronic properties

Abstract

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