BaZrxy1-xO3-δ and BaCe 1-x-zZrxyzO3-δ proton conductors for intermediate temperature solid oxide fuel cells (IT-SOFCs)

A. D'Epifanio; E. Fabbri; E. Di Bartolomeo; S. Licoccia; E. Traversa

doi:10.1149/1.2729353

BaZr_xy_1-xO_3-δ and BaCe _1-x-zZr_xy_zO_3-δ proton conductors for intermediate temperature solid oxide fuel cells (IT-SOFCs)

A. D'Epifanio^*, E. Fabbri, E. Di Bartolomeo, S. Licoccia, E. Traversa

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

6 Scopus citations

Abstract

A wet chemistry route to produce barium zirconate BaZr_xY _1-xO_3-δ (BZY) and barium cerium zirconate BaCe _1-x-zZr_xY_zO_3-δ (BCZY) with controlled chemical structure and microstructural properties was optimized. A single phase was obtained at temperatures as low as 1100°C for BZY and 1200°C for BCZY. To verify their chemical stability, all the calcined oxides were exposed to CO₂ and the phase composition of the resulting specimens was investigated using X-ray diffraction (XRD) analysis Dense electrolytes were obtained sintering BZY and BCZY pellets at 1600°C for 10 hours, as shown from field emission scanning electron microscopy (FE-SEM) images. To compare the cell performance of the different oxides, fuel cell polarization curves on symmetric (Pt/BZY/Pt and Pt/BCZY/Pt) cells were measured at 700°C

Original language	English (US)
Title of host publication	ECS Transactions - 10th International Symposium on Solid Oxide Fuel Cells, SOFC-X
Pages	2337-2342
Number of pages	6
Edition	1 PART 2
DOIs	https://doi.org/10.1149/1.2729353
State	Published - 2007
Externally published	Yes
Event	10th International Symposium on Solid Oxide Fuel Cells, SOFC-X - , Japan Duration: Jun 3 2007 → Jun 8 2007

Publication series

Name	ECS Transactions
Number	1 PART 2
Volume	7
ISSN (Print)	1938-5862
ISSN (Electronic)	1938-6737

Other

Other	10th International Symposium on Solid Oxide Fuel Cells, SOFC-X
Country/Territory	Japan
Period	06/3/07 → 06/8/07

ASJC Scopus subject areas

General Engineering

Access to Document

10.1149/1.2729353

Cite this

D'Epifanio, A., Fabbri, E., Di Bartolomeo, E., Licoccia, S., & Traversa, E. (2007). BaZr_xy_1-xO_3-δ and BaCe _1-x-zZr_xy_zO_3-δ proton conductors for intermediate temperature solid oxide fuel cells (IT-SOFCs). In ECS Transactions - 10th International Symposium on Solid Oxide Fuel Cells, SOFC-X (1 PART 2 ed., pp. 2337-2342). (ECS Transactions; Vol. 7, No. 1 PART 2). https://doi.org/10.1149/1.2729353

@inproceedings{2b01732373fe4421bc34556ac8d3136d,

title = "BaZrxy1-xO3-δ and BaCe 1-x-zZrxyzO3-δ proton conductors for intermediate temperature solid oxide fuel cells (IT-SOFCs)",

abstract = "A wet chemistry route to produce barium zirconate BaZrxY 1-xO3-δ (BZY) and barium cerium zirconate BaCe 1-x-zZrxYzO3-δ (BCZY) with controlled chemical structure and microstructural properties was optimized. A single phase was obtained at temperatures as low as 1100°C for BZY and 1200°C for BCZY. To verify their chemical stability, all the calcined oxides were exposed to CO2 and the phase composition of the resulting specimens was investigated using X-ray diffraction (XRD) analysis Dense electrolytes were obtained sintering BZY and BCZY pellets at 1600°C for 10 hours, as shown from field emission scanning electron microscopy (FE-SEM) images. To compare the cell performance of the different oxides, fuel cell polarization curves on symmetric (Pt/BZY/Pt and Pt/BCZY/Pt) cells were measured at 700°C",

author = "A. D'Epifanio and E. Fabbri and {Di Bartolomeo}, E. and S. Licoccia and E. Traversa",

year = "2007",

doi = "10.1149/1.2729353",

language = "English (US)",

isbn = "9781566775564",

series = "ECS Transactions",

number = "1 PART 2",

pages = "2337--2342",

booktitle = "ECS Transactions - 10th International Symposium on Solid Oxide Fuel Cells, SOFC-X",

edition = "1 PART 2",

note = "10th International Symposium on Solid Oxide Fuel Cells, SOFC-X ; Conference date: 03-06-2007 Through 08-06-2007",

}

D'Epifanio, A, Fabbri, E, Di Bartolomeo, E, Licoccia, S & Traversa, E 2007, BaZr_xy_1-xO_3-δ and BaCe _1-x-zZr_xy_zO_3-δ proton conductors for intermediate temperature solid oxide fuel cells (IT-SOFCs). in ECS Transactions - 10th International Symposium on Solid Oxide Fuel Cells, SOFC-X. 1 PART 2 edn, ECS Transactions, no. 1 PART 2, vol. 7, pp. 2337-2342, 10th International Symposium on Solid Oxide Fuel Cells, SOFC-X, Japan, 06/3/07. https://doi.org/10.1149/1.2729353

BaZr_xy_1-xO_3-δ and BaCe _1-x-zZr_xy_zO_3-δ proton conductors for intermediate temperature solid oxide fuel cells (IT-SOFCs). / D'Epifanio, A.; Fabbri, E.; Di Bartolomeo, E. et al.
ECS Transactions - 10th International Symposium on Solid Oxide Fuel Cells, SOFC-X. 1 PART 2. ed. 2007. p. 2337-2342 (ECS Transactions; Vol. 7, No. 1 PART 2).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - BaZrxy1-xO3-δ and BaCe 1-x-zZrxyzO3-δ proton conductors for intermediate temperature solid oxide fuel cells (IT-SOFCs)

AU - D'Epifanio, A.

AU - Fabbri, E.

AU - Di Bartolomeo, E.

AU - Licoccia, S.

AU - Traversa, E.

PY - 2007

Y1 - 2007

N2 - A wet chemistry route to produce barium zirconate BaZrxY 1-xO3-δ (BZY) and barium cerium zirconate BaCe 1-x-zZrxYzO3-δ (BCZY) with controlled chemical structure and microstructural properties was optimized. A single phase was obtained at temperatures as low as 1100°C for BZY and 1200°C for BCZY. To verify their chemical stability, all the calcined oxides were exposed to CO2 and the phase composition of the resulting specimens was investigated using X-ray diffraction (XRD) analysis Dense electrolytes were obtained sintering BZY and BCZY pellets at 1600°C for 10 hours, as shown from field emission scanning electron microscopy (FE-SEM) images. To compare the cell performance of the different oxides, fuel cell polarization curves on symmetric (Pt/BZY/Pt and Pt/BCZY/Pt) cells were measured at 700°C

AB - A wet chemistry route to produce barium zirconate BaZrxY 1-xO3-δ (BZY) and barium cerium zirconate BaCe 1-x-zZrxYzO3-δ (BCZY) with controlled chemical structure and microstructural properties was optimized. A single phase was obtained at temperatures as low as 1100°C for BZY and 1200°C for BCZY. To verify their chemical stability, all the calcined oxides were exposed to CO2 and the phase composition of the resulting specimens was investigated using X-ray diffraction (XRD) analysis Dense electrolytes were obtained sintering BZY and BCZY pellets at 1600°C for 10 hours, as shown from field emission scanning electron microscopy (FE-SEM) images. To compare the cell performance of the different oxides, fuel cell polarization curves on symmetric (Pt/BZY/Pt and Pt/BCZY/Pt) cells were measured at 700°C

UR - http://www.scopus.com/inward/record.url?scp=45249092767&partnerID=8YFLogxK

U2 - 10.1149/1.2729353

DO - 10.1149/1.2729353

M3 - Conference contribution

AN - SCOPUS:45249092767

SN - 9781566775564

SN - 9781566775540

T3 - ECS Transactions

SP - 2337

EP - 2342

BT - ECS Transactions - 10th International Symposium on Solid Oxide Fuel Cells, SOFC-X

T2 - 10th International Symposium on Solid Oxide Fuel Cells, SOFC-X

Y2 - 3 June 2007 through 8 June 2007

ER -