Basic zeolites as catalysts in the N-alkylation of imidazole: Activation by microwave irradiation

L. Costarrosa, J. Ruiz-Martínez, R. V.R.A. Rios, J. Silvestre-Albero, M. L. Rojas-Cervantes, A. Sepúlveda-Escribano

Research output: Contribution to journalArticlepeer-review

6 Scopus citations


The alkylation of imidazole (C3H4N2) with different alkyl halides, such as 1-Br-butane, 2-Br-butane and 1-Br-hexane, has been carried out in the absence of solvent using basic zeolites as catalysts. Catalysts were prepared by cation exchange of a commercial NaX zeolite with different alkaline-earth cations (Ca, Sr and Ba). The resulting zeolites were characterised by N2 (77 K) and CO2 (273 K) adsorption, immersion calorimetry, CO2 adsorption calorimetry and CO2 temperature-programmed desorption experiments. The influence of the irradiation time and power and the alkaline-earth exchanged cation on the catalytic activity has been studied. Conversion values as high as 95% and selectivity values of 100% were obtained at 700 W in only 5 min in most of the cases when 1-Br-butane and 2-Br-butane were used as alkylating agents. In general, NaX is the best catalyst in most of the reaction conditions studied. © 2008 Elsevier Inc. All rights reserved.
Original languageEnglish (US)
JournalMicroporous and Mesoporous Materials
Issue number1-2
StatePublished - Apr 1 2009
Externally publishedYes

Bibliographical note

Generated from Scopus record by KAUST IRTS on 2019-08-08


Dive into the research topics of 'Basic zeolites as catalysts in the N-alkylation of imidazole: Activation by microwave irradiation'. Together they form a unique fingerprint.

Cite this