Assembly of Metal-Organic Frameworks (MOFs) based on indium-trimer building blocks: A porous MOF with soc topology and high hydrogen storage

Yunling Liu*, Jarrod F. Eubank, Amy J. Cairns, Juergen Eckert, Victor Ch Kravtsov, Ryan Luebke, Mohamed Eddaoudi

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

662 Scopus citations

Abstract

(Figure Presented) The key to soc-cess: The trimer building block [In 3O(CO2)6] and a tetracarboxylate organic linker assemble into a novel porous metal-organic framework (see picture; In green, C gray, N blue, O red; cavity: yellow sphere) having an unprecedented soc topology (soc = square-octahedron) and high H2 uptake.

Original languageEnglish (US)
Pages (from-to)3278-3283
Number of pages6
JournalAngewandte Chemie - International Edition
Volume46
Issue number18
DOIs
StatePublished - 2007
Externally publishedYes

Keywords

  • Hydrogen storage
  • Indium
  • Metal-organic frameworks
  • Molecular building blocks
  • Porous materials

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry

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