Assembly of metal-organic frameworks from large organic and inorganic secondary building units: New examples and simplifying principles for complex structures

J. Kim; B. Chen; T. M. Reineke; H. Li; M. Eddaoudi; D. B. Moler; M. O'Keeffe; O. M. Yaghi

doi:10.1021/ja010825o

Assembly of metal-organic frameworks from large organic and inorganic secondary building units: New examples and simplifying principles for complex structures

J. Kim, B. Chen, T. M. Reineke, H. Li, M. Eddaoudi, D. B. Moler, M. O'Keeffe, O. M. Yaghi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

848 Scopus citations

Abstract

The secondary building unit (SBU) has been identified as a useful tool in the analysis of complex metal-organic frameworks (MOFs). We illustrate its applicability to rationalizing MOF crystal structures by analysis of nine new MOFs which have been characterized by single-crystal X-ray diffraction. Tetrahedral SBUs in Zn(ADC)₂·(HTEA)₂ (MOF-31), Cd(ATC) ·[Cd(H₂O)₆](H₂O)₅ (MOF-32), and Zn₂(ATB)(H₂O)·(H₂O)₃ (DMF)₃ (MOF-33) are linked into diamond networks, while those of Ni₂(ATC)(H₂O)₄· (H₂O)₄·(H₂O)₄ (MOF-34) have the structure of the Al network in SrAl₂. Frameworks constructed from less symmetric tetrahedral SBUs have the Ga network of CaGa₂O₄ as illustrated by Zn₂(ATC)·(C₂H₅OH)₂ (H₂O)₂ (MOF-35) structure. Squares and tetrahedral SBUs in Zn₂(MTB)(H₂O)₂·(DMF)₆ (H₂O)₅ (MOF-36) are linked into the PtS network, which is the simplest structure type known for the assembly of these shapes. The octahedral SBUs found in Zn₂(NDC)₃·[(HTEA)(DEF)(ClBz)]₂ (MOF-37) form the most common structure for linking octahedral shapes, namely, the boron network in CaB₆. New structure types for linking triangular and trigonal prismatic SBUs are found in Zn₃O(BTC)₂·(HTEA)₂ (MOF-38) and Zn₃O(HBTB)₂(H₂O)·(DMF)_0.5 (H₂O)₃ (MOF-39). The synthesis, crystal structure, and structure analysis using the SBU approach are presented for each MOF.

Original language	English (US)
Pages (from-to)	8239-8247
Number of pages	9
Journal	Journal of the American Chemical Society
Volume	123
Issue number	34
DOIs	https://doi.org/10.1021/ja010825o
State	Published - 2001
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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@article{a41dd80688994000af193a7d29013355,

title = "Assembly of metal-organic frameworks from large organic and inorganic secondary building units: New examples and simplifying principles for complex structures",

abstract = "The secondary building unit (SBU) has been identified as a useful tool in the analysis of complex metal-organic frameworks (MOFs). We illustrate its applicability to rationalizing MOF crystal structures by analysis of nine new MOFs which have been characterized by single-crystal X-ray diffraction. Tetrahedral SBUs in Zn(ADC)2·(HTEA)2 (MOF-31), Cd(ATC) ·[Cd(H2O)6](H2O)5 (MOF-32), and Zn2(ATB)(H2O)·(H2O)3 (DMF)3 (MOF-33) are linked into diamond networks, while those of Ni2(ATC)(H2O)4· (H2O)4·(H2O)4 (MOF-34) have the structure of the Al network in SrAl2. Frameworks constructed from less symmetric tetrahedral SBUs have the Ga network of CaGa2O4 as illustrated by Zn2(ATC)·(C2H5OH)2 (H2O)2 (MOF-35) structure. Squares and tetrahedral SBUs in Zn2(MTB)(H2O)2·(DMF)6 (H2O)5 (MOF-36) are linked into the PtS network, which is the simplest structure type known for the assembly of these shapes. The octahedral SBUs found in Zn2(NDC)3·[(HTEA)(DEF)(ClBz)]2 (MOF-37) form the most common structure for linking octahedral shapes, namely, the boron network in CaB6. New structure types for linking triangular and trigonal prismatic SBUs are found in Zn3O(BTC)2·(HTEA)2 (MOF-38) and Zn3O(HBTB)2(H2O)·(DMF)0.5 (H2O)3 (MOF-39). The synthesis, crystal structure, and structure analysis using the SBU approach are presented for each MOF.",

author = "J. Kim and B. Chen and Reineke, {T. M.} and H. Li and M. Eddaoudi and Moler, {D. B.} and M. O'Keeffe and Yaghi, {O. M.}",

year = "2001",

doi = "10.1021/ja010825o",

language = "English (US)",

volume = "123",

pages = "8239--8247",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "34",

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TY - JOUR

T1 - Assembly of metal-organic frameworks from large organic and inorganic secondary building units

T2 - New examples and simplifying principles for complex structures

AU - Kim, J.

AU - Chen, B.

AU - Reineke, T. M.

AU - Li, H.

AU - Eddaoudi, M.

AU - Moler, D. B.

AU - O'Keeffe, M.

AU - Yaghi, O. M.

PY - 2001

Y1 - 2001

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AB - The secondary building unit (SBU) has been identified as a useful tool in the analysis of complex metal-organic frameworks (MOFs). We illustrate its applicability to rationalizing MOF crystal structures by analysis of nine new MOFs which have been characterized by single-crystal X-ray diffraction. Tetrahedral SBUs in Zn(ADC)2·(HTEA)2 (MOF-31), Cd(ATC) ·[Cd(H2O)6](H2O)5 (MOF-32), and Zn2(ATB)(H2O)·(H2O)3 (DMF)3 (MOF-33) are linked into diamond networks, while those of Ni2(ATC)(H2O)4· (H2O)4·(H2O)4 (MOF-34) have the structure of the Al network in SrAl2. Frameworks constructed from less symmetric tetrahedral SBUs have the Ga network of CaGa2O4 as illustrated by Zn2(ATC)·(C2H5OH)2 (H2O)2 (MOF-35) structure. Squares and tetrahedral SBUs in Zn2(MTB)(H2O)2·(DMF)6 (H2O)5 (MOF-36) are linked into the PtS network, which is the simplest structure type known for the assembly of these shapes. The octahedral SBUs found in Zn2(NDC)3·[(HTEA)(DEF)(ClBz)]2 (MOF-37) form the most common structure for linking octahedral shapes, namely, the boron network in CaB6. New structure types for linking triangular and trigonal prismatic SBUs are found in Zn3O(BTC)2·(HTEA)2 (MOF-38) and Zn3O(HBTB)2(H2O)·(DMF)0.5 (H2O)3 (MOF-39). The synthesis, crystal structure, and structure analysis using the SBU approach are presented for each MOF.

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U2 - 10.1021/ja010825o

DO - 10.1021/ja010825o

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 34

ER -

Assembly of metal-organic frameworks from large organic and inorganic secondary building units: New examples and simplifying principles for complex structures

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