Assembly of Atomically Precise Silver Nanoclusters into Nanocluster-Based Frameworks

Mohammad Jaber Alhilaly; Renwu Huang; Rounak Naphade; Badriah Jaber Alamer; Mohamed N. Hedhili; Abdul-Hamid M. Emwas; Partha Maity; Jun Yin; Aleksander Shkurenko; Omar F. Mohammed; Mohamed Eddaoudi; Osman Bakr

doi:10.1021/jacs.9b02486

Assembly of Atomically Precise Silver Nanoclusters into Nanocluster-Based Frameworks

Mohammad Jaber Alhilaly, Renwu Huang, Rounak Naphade, Badriah Jaber Alamer, Mohamed N. Hedhili, Abdul-Hamid M. Emwas, Partha Maity, Jun Yin, Aleksander Shkurenko, Omar F. Mohammed, Mohamed Eddaoudi, Osman Bakr

Research output: Contribution to journal › Article › peer-review

146 Scopus citations

Abstract

Here, we demonstrate an approach to synthesizing and structurally characterizing three atomically precise anion-templated silver thiolate nanoclusters, two of which form one- and two-dimensional structural frameworks composed of bipyridine-linked nanocluster nodes (referred to as nanocluster-based frameworks, NCFs). We describe the critical role of the chloride (Cl−) template in controlling the nanocluster’s nuclearity with atomic precision and the effect of a single Ag atom difference in the nanocluster’s size in controlling the NCF dimensionality, modulating the optical properties, and improving the thermal stability. With atomically precise assembly and size control, nanoclusters could be widely adopted as building blocks for the construction of tunable cluster-based framework materials.

Original language	English (US)
Pages (from-to)	9585-9592
Number of pages	8
Journal	Journal of the American Chemical Society
Volume	141
Issue number	24
DOIs	https://doi.org/10.1021/jacs.9b02486
State	Published - May 28 2019

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The authors sincerely thank the following people for their help and dedication at various stages of this project: Ayalew Assen, Karim Adil, and Osama Shekhah. The financial support for this work was provided by KAUST.

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10.1021/jacs.9b02486

https://repository.kaust.edu.sa/bitstream/10754/656042/1/jacs.9b02486.pdf

Cite this

@article{1b71289806304d2793e503b5c73f8c9b,

title = "Assembly of Atomically Precise Silver Nanoclusters into Nanocluster-Based Frameworks",

abstract = "Here, we demonstrate an approach to synthesizing and structurally characterizing three atomically precise anion-templated silver thiolate nanoclusters, two of which form one- and two-dimensional structural frameworks composed of bipyridine-linked nanocluster nodes (referred to as nanocluster-based frameworks, NCFs). We describe the critical role of the chloride (Cl−) template in controlling the nanocluster{\textquoteright}s nuclearity with atomic precision and the effect of a single Ag atom difference in the nanocluster{\textquoteright}s size in controlling the NCF dimensionality, modulating the optical properties, and improving the thermal stability. With atomically precise assembly and size control, nanoclusters could be widely adopted as building blocks for the construction of tunable cluster-based framework materials.",

author = "Alhilaly, {Mohammad Jaber} and Renwu Huang and Rounak Naphade and Alamer, {Badriah Jaber} and Hedhili, {Mohamed N.} and Emwas, {Abdul-Hamid M.} and Partha Maity and Jun Yin and Aleksander Shkurenko and Mohammed, {Omar F.} and Mohamed Eddaoudi and Osman Bakr",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors sincerely thank the following people for their help and dedication at various stages of this project: Ayalew Assen, Karim Adil, and Osama Shekhah. The financial support for this work was provided by KAUST.",

year = "2019",

month = may,

day = "28",

doi = "10.1021/jacs.9b02486",

language = "English (US)",

volume = "141",

pages = "9585--9592",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "24",

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TY - JOUR

T1 - Assembly of Atomically Precise Silver Nanoclusters into Nanocluster-Based Frameworks

AU - Alhilaly, Mohammad Jaber

AU - Huang, Renwu

AU - Naphade, Rounak

AU - Alamer, Badriah Jaber

AU - Hedhili, Mohamed N.

AU - Emwas, Abdul-Hamid M.

AU - Maity, Partha

AU - Yin, Jun

AU - Shkurenko, Aleksander

AU - Mohammed, Omar F.

AU - Eddaoudi, Mohamed

AU - Bakr, Osman

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors sincerely thank the following people for their help and dedication at various stages of this project: Ayalew Assen, Karim Adil, and Osama Shekhah. The financial support for this work was provided by KAUST.

PY - 2019/5/28

Y1 - 2019/5/28

N2 - Here, we demonstrate an approach to synthesizing and structurally characterizing three atomically precise anion-templated silver thiolate nanoclusters, two of which form one- and two-dimensional structural frameworks composed of bipyridine-linked nanocluster nodes (referred to as nanocluster-based frameworks, NCFs). We describe the critical role of the chloride (Cl−) template in controlling the nanocluster’s nuclearity with atomic precision and the effect of a single Ag atom difference in the nanocluster’s size in controlling the NCF dimensionality, modulating the optical properties, and improving the thermal stability. With atomically precise assembly and size control, nanoclusters could be widely adopted as building blocks for the construction of tunable cluster-based framework materials.

AB - Here, we demonstrate an approach to synthesizing and structurally characterizing three atomically precise anion-templated silver thiolate nanoclusters, two of which form one- and two-dimensional structural frameworks composed of bipyridine-linked nanocluster nodes (referred to as nanocluster-based frameworks, NCFs). We describe the critical role of the chloride (Cl−) template in controlling the nanocluster’s nuclearity with atomic precision and the effect of a single Ag atom difference in the nanocluster’s size in controlling the NCF dimensionality, modulating the optical properties, and improving the thermal stability. With atomically precise assembly and size control, nanoclusters could be widely adopted as building blocks for the construction of tunable cluster-based framework materials.

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UR - http://pubs.acs.org/doi/10.1021/jacs.9b02486

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U2 - 10.1021/jacs.9b02486

DO - 10.1021/jacs.9b02486

M3 - Article

C2 - 31135146

SN - 0002-7863

VL - 141

SP - 9585

EP - 9592

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 24

ER -

Assembly of Atomically Precise Silver Nanoclusters into Nanocluster-Based Frameworks

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CCDC 1893799: Experimental Crystal Structure Determination : catena-(tetrakis(mu-4,4'-bipyridine)-bis(mu-chloro)-octakis(mu-t-butylsulfido)-hexakis(mu-trifluoroacetato)-bis(dimethylformamide)-tetrakis(trifluoroacetato)-octacosa-silver dimethylformamide unk

CCDC 1893797: Experimental Crystal Structure Determination : octakis(mu-t-butylsulfido)-(mu-chloro)-bis(mu-dimethylformamide)-heptakis(mu-trifluoroacetato)-aqua-bis(dimethylformamide)-hexadeca-silver dimethylformamide solvate

CCDC 1893798: Experimental Crystal Structure Determination : catena-((mu-chloro)-octakis(mu-t-butylsulfido)-tetrakis(mu-trifluoroacetato)-bis(mu-4,4'-bipyridine)-bis(dimethylformamide)-bis(trifluoroacetato)-pentadeca-silver dimethylformamide solvate monohy

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Assembly of Atomically Precise Silver Nanoclusters into Nanocluster-Based Frameworks

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1893799: Experimental Crystal Structure Determination : catena-(tetrakis(mu-4,4'-bipyridine)-bis(mu-chloro)-octakis(mu-t-butylsulfido)-hexakis(mu-trifluoroacetato)-bis(dimethylformamide)-tetrakis(trifluoroacetato)-octacosa-silver dimethylformamide unk

CCDC 1893797: Experimental Crystal Structure Determination : octakis(mu-t-butylsulfido)-(mu-chloro)-bis(mu-dimethylformamide)-heptakis(mu-trifluoroacetato)-aqua-bis(dimethylformamide)-hexadeca-silver dimethylformamide solvate

CCDC 1893798: Experimental Crystal Structure Determination : catena-((mu-chloro)-octakis(mu-t-butylsulfido)-tetrakis(mu-trifluoroacetato)-bis(mu-4,4'-bipyridine)-bis(dimethylformamide)-bis(trifluoroacetato)-pentadeca-silver dimethylformamide solvate monohy

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