Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst

Seema Arun Ghorpade; Dinesh Sawant; Dominik Renn; Anna Zernickel; weiyuan du; Nethi Sekar; Jörg Eppinger

doi:10.1039/c8nj00660a

Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst

Seema Arun Ghorpade, Dinesh Sawant, Dominik Renn, Anna Zernickel, weiyuan du, Nethi Sekar, Jörg Eppinger

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Abstract

Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.

Original language	English (US)
Pages (from-to)	6210-6214
Number of pages	5
Journal	New Journal of Chemistry
Volume	42
Issue number	8
DOIs	https://doi.org/10.1039/c8nj00660a
State	Published - 2018

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): FIC/2010/07
Acknowledgements: The author Seema Arun Ghorpade is thankful to the Institute of Chemical Technology, Matunga, Mumbai and Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship (IF110631). This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). Authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.

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10.1039/c8nj00660a

https://repository.kaust.edu.sa/bitstream/10754/627385/1/c8nj00660a.pdf

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title = "Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst",

abstract = "Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.",

author = "Ghorpade, {Seema Arun} and Dinesh Sawant and Dominik Renn and Anna Zernickel and weiyuan du and Nethi Sekar and J{\"o}rg Eppinger",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/07 Acknowledgements: The author Seema Arun Ghorpade is thankful to the Institute of Chemical Technology, Matunga, Mumbai and Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship (IF110631). This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). Authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.",

year = "2018",

doi = "10.1039/c8nj00660a",

language = "English (US)",

volume = "42",

pages = "6210--6214",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

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T1 - Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst

AU - Ghorpade, Seema Arun

AU - Sawant, Dinesh

AU - Renn, Dominik

AU - Zernickel, Anna

AU - du, weiyuan

AU - Sekar, Nethi

AU - Eppinger, Jörg

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/07 Acknowledgements: The author Seema Arun Ghorpade is thankful to the Institute of Chemical Technology, Matunga, Mumbai and Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship (IF110631). This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). Authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.

PY - 2018

Y1 - 2018

N2 - Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.

AB - Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.

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U2 - 10.1039/c8nj00660a

DO - 10.1039/c8nj00660a

M3 - Article

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JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 8

ER -

Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst

Abstract

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