Analyzing solid fossil-fuel pitches by a combination of Soxhlet extraction and Fourier transform ion cyclotron resonance mass spectrometry

Wen Zhang, Klaus Müllen

    Research output: Contribution to journalArticlepeer-review

    17 Scopus citations

    Abstract

    Solid fossil-fuel derived pitches serve as potential feedstocks for the preparation of high-performance carbons materials, which is, however, hampered by the lack of sound knowledge on the molecular composition and structure of pitches. Soxhlet extraction and ultrahigh-resolution Fourier transform ion cyclotron resonance (FT ICR) mass spectrometry were combined to characterize a petroleum pitch and a coal tar pitch, as well as their toluene-soluble and toluene-insoluble fractions. Important information can be gained on the chemical nature of polycyclic aromatic compounds such as pure hydrocarbons and various N-, O- or S-derivatives, as well as the relative abundance of each molecular structure in terms of carbon number vs. hydrogen number. This is the first time that the heteroatom-containing and pure hydrocarbon aromatics were clearly differentiated in such solid pitch samples. The differences among the toluene-soluble fraction, toluene-insoluble fraction, and unfractionated intact sample of both the petroleum pitch and coal tar pitch could be systematically compared at a molecular level. Insight into the molecular structures may provide a rational basis for the use of such carbon-rich materials for the fabrication of nanographenes, organic light-emitting diodes, and carbon fibers.
    Original languageEnglish (US)
    Pages (from-to)414-421
    Number of pages8
    JournalCarbon
    Volume167
    DOIs
    StatePublished - May 21 2020

    Bibliographical note

    KAUST Repository Item: Exported on 2020-10-01
    Acknowledgements: The authors are grateful to RÜTGERS Basic Aromatics GmbH, Castrop-Rauxel, Germany for supplying the solid pitch samples. This research used resources of the Core Labs of King Abdullah University of Science and Technology (KAUST).

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