Analysis of the deactivation of ZSM-5 catalyst during MTO reaction in a periodic operating fixed bed reactor

Héctor Vicente, Tomás Cordero-Lanzac, Ana Guadalupe Gayubo, Pedro Castaño

Research output: Chapter in Book/Report/Conference proceedingConference contribution


A set of methanol to olefins (MTO) reactions has been performed in a fixed bed periodic operating reactor with a low acidic ZSM-5 zeolite catalyst. The experimental set-up of the periodic reactor allows the operation in fast heating cooling cycles, therefore obtaining coke formed by distinct pathways. The conversion of oxygenates and yields of products have been analyzed for both conventional fixed bed and periodic operating reactor and the deactivated catalyst has been characterized by different methods and then compared to those obtained for the fresh catalyst. Our results show that periodic operation is a suitable option for extending the lifetime of the catalyst compared to the conventional steady operating MTO reaction. The stability increase is proportional to the length of the oscillation period. The analysis of the coke samples obtained with periodic operation combined with the information obtained by improved techniques such as catalyzed combustion of coke open a new approach to understanding the catalyst deactivation in MTO reaction.
Original languageEnglish (US)
Title of host publication14th Mediterranean Congress of Chemical Engineering (MeCCE14) Abstracts Publication
PublisherGrupo Pacífico
ISBN (Print)9788409252442
StatePublished - Nov 16 2020

Bibliographical note

KAUST Repository Item: Exported on 2020-11-18
Acknowledgements: Authors fully acknowledge the financial support received from the Ministry of Economy and Competitiveness of the Spanish Government (MINECO), through project CTQ2016-79646-P, The Basque Government (IT748-13) and ERDF funds. Héctor Vicente is grateful for the Ph. D. grant from the Basque Government.


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