TY - JOUR
T1 - An Update on Formic Acid Dehydrogenation by Homogeneous Catalysis
AU - Guan, Chao
AU - Pan, Yupeng
AU - Zhang, Tonghuan
AU - Ajitha, Manjaly John
AU - Huang, Kuo-Wei
N1 - KAUST Repository Item: Exported on 2020-04-23
Acknowledgements: This work was supportedby King AbdullahUniversityof Scienceand Technology(KAUST).
PY - 2020/2/27
Y1 - 2020/2/27
N2 - Formic acid (FA) has been extensively studied as one of the most promising hydrogen energy carriers today.The catalytic decarboxylation of FA ideally leads to the formation of CO2 and H2 that can be applied in fuel cells. A large number of transition-metal based homogeneous cata-lysts with high activity and selectivity have been reported for the selective FA dehydrogentaion. In this review,we discussed the recent development of C,N/N,N-ligand and pincer ligand-based homogeneous catalysts for the FA dehydrogenation reaction.Some representative catalysts are further evaluated by the CON/COF assessment(catalyston-cost number)/(catalyston-costfrequency).Conclusive re-marks are provided with future challenges and opportunities.
AB - Formic acid (FA) has been extensively studied as one of the most promising hydrogen energy carriers today.The catalytic decarboxylation of FA ideally leads to the formation of CO2 and H2 that can be applied in fuel cells. A large number of transition-metal based homogeneous cata-lysts with high activity and selectivity have been reported for the selective FA dehydrogentaion. In this review,we discussed the recent development of C,N/N,N-ligand and pincer ligand-based homogeneous catalysts for the FA dehydrogenation reaction.Some representative catalysts are further evaluated by the CON/COF assessment(catalyston-cost number)/(catalyston-costfrequency).Conclusive re-marks are provided with future challenges and opportunities.
UR - http://hdl.handle.net/10754/661773
UR - http://doi.wiley.com/10.1002/asia.202000191
U2 - 10.1002/asia.201901676
DO - 10.1002/asia.201901676
M3 - Article
C2 - 32030903
SN - 1861-4728
JO - Chemistry - An Asian Journal
JF - Chemistry - An Asian Journal
ER -