An Unexpected Boron Rearrangement Leads to a Fluorogenic and Colorimetric BODIPY Probe

Jean Michel Merkes; Gerhard Raabe; Fabian Kiessling; Magnus Rueping; Srinivas Banala

doi:10.1002/adom.202202601

An Unexpected Boron Rearrangement Leads to a Fluorogenic and Colorimetric BODIPY Probe

Jean Michel Merkes, Gerhard Raabe, Fabian Kiessling, Magnus Rueping, Srinivas Banala

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The isolation and characterization of a kinetically stable oxadiazaborinine (ODB) dye are described, which undergoes an unexpected thermal boron rearrangement with a color change and increase in fluorescence. This controllable reaction allows for the use as a practical time-temperature indicator probe with the advantages of photostability, non-reversibility, and environmental friendliness.

Original language	English (US)
Pages (from-to)	2202601
Journal	Advanced Optical Materials
DOIs	https://doi.org/10.1002/adom.202202601
State	Published - Jan 8 2023

Bibliographical note

KAUST Repository Item: Exported on 2023-01-13
Acknowledgements: This research was supported by the Excellence Initiative from German federal and state governments through I3TM Seed Fund Program, I3TM Step2Projects and Exploratory Research Space (S.B); German Science Foundation (DFG) in the framework of the Research Training Group 2375 “Tumor-targeted Drug Delivery” grant 331065168 (F.K.). Open access funding enabled and organized by Projekt DEAL.

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics

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10.1002/adom.202202601

https://repository.kaust.edu.sa/bitstream/10754/687006/1/Advanced%20Optical%20Materials%20-%202023%20-%20Merkes%20-%20An%20Unexpected%20Boron%20Rearrangement%20Leads%20to%20a%20Fluorogenic%20and%20Colorimetric.pdf

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title = "An Unexpected Boron Rearrangement Leads to a Fluorogenic and Colorimetric BODIPY Probe",

abstract = "The isolation and characterization of a kinetically stable oxadiazaborinine (ODB) dye are described, which undergoes an unexpected thermal boron rearrangement with a color change and increase in fluorescence. This controllable reaction allows for the use as a practical time-temperature indicator probe with the advantages of photostability, non-reversibility, and environmental friendliness.",

author = "Merkes, {Jean Michel} and Gerhard Raabe and Fabian Kiessling and Magnus Rueping and Srinivas Banala",

note = "KAUST Repository Item: Exported on 2023-01-13 Acknowledgements: This research was supported by the Excellence Initiative from German federal and state governments through I3TM Seed Fund Program, I3TM Step2Projects and Exploratory Research Space (S.B); German Science Foundation (DFG) in the framework of the Research Training Group 2375 “Tumor-targeted Drug Delivery” grant 331065168 (F.K.). Open access funding enabled and organized by Projekt DEAL.",

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doi = "10.1002/adom.202202601",

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AU - Merkes, Jean Michel

AU - Raabe, Gerhard

AU - Kiessling, Fabian

AU - Rueping, Magnus

AU - Banala, Srinivas

N1 - KAUST Repository Item: Exported on 2023-01-13 Acknowledgements: This research was supported by the Excellence Initiative from German federal and state governments through I3TM Seed Fund Program, I3TM Step2Projects and Exploratory Research Space (S.B); German Science Foundation (DFG) in the framework of the Research Training Group 2375 “Tumor-targeted Drug Delivery” grant 331065168 (F.K.). Open access funding enabled and organized by Projekt DEAL.

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Y1 - 2023/1/8

N2 - The isolation and characterization of a kinetically stable oxadiazaborinine (ODB) dye are described, which undergoes an unexpected thermal boron rearrangement with a color change and increase in fluorescence. This controllable reaction allows for the use as a practical time-temperature indicator probe with the advantages of photostability, non-reversibility, and environmental friendliness.

AB - The isolation and characterization of a kinetically stable oxadiazaborinine (ODB) dye are described, which undergoes an unexpected thermal boron rearrangement with a color change and increase in fluorescence. This controllable reaction allows for the use as a practical time-temperature indicator probe with the advantages of photostability, non-reversibility, and environmental friendliness.

UR - http://hdl.handle.net/10754/687006

UR - https://onlinelibrary.wiley.com/doi/10.1002/adom.202202601

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JO - Advanced Optical Materials

JF - Advanced Optical Materials

ER -

An Unexpected Boron Rearrangement Leads to a Fluorogenic and Colorimetric BODIPY Probe

Abstract

Bibliographical note

ASJC Scopus subject areas

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