An Anode-Free Zn–MnO2 Battery

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Aqueous Zn-based batteries are attractive because of the low cost and high theoretical capacity of the Zn metal anode. However, the Zn-based batteries developed so far utilize an excess amount of Zn (i.e., thick Zn metal anode), which decreases the energy density of the whole battery. Herein, we demonstrate an anode-free design (i.e., zero-excess Zn), which is enabled by employing a nanocarbon nucleation layer. Electrochemical studies show that this design allows for uniform Zn electrodeposition with high efficiency and stability over a range of current densities and plating capacities. Using this anode-free configuration, we showcase a Zn-MnO2 battery prototype, showing 68.2% capacity retention after 80 cycles. Our anode-free design opens a new direction for implementing aqueous Zn-based batteries in energy storage systems.
Original languageEnglish (US)
JournalNano Letters
StatePublished - Jan 20 2021

Bibliographical note

KAUST Repository Item: Exported on 2021-02-03
Acknowledged KAUST grant number(s): OSR-CRG2018-3735
Acknowledgements: Research reported in this work was supported by King Abdullah University of Science and Technology (KAUST) under the KAUST Stanford competitive research grant number: OSR-CRG2018-3735.


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