[Al12P13O52]3-[(CH2)6N4H3]3+: An anionic aluminophosphate molecular sieve with bronsted acidity

W. Yan; J. Yu; R. Xu; G. Zhu; F. Xiao; Y. Han; K. Sugiyama; O. Terasaki

doi:10.1021/cm000280h

[Al₁₂P₁₃O₅₂]^3-[(CH₂)₆N₄H₃]³⁺: An anionic aluminophosphate molecular sieve with bronsted acidity

W. Yan, J. Yu, R. Xu^*, G. Zhu, F. Xiao, Y. Han, K. Sugiyama, O. Terasaki

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

The first anionic aluminophosphate molecular sieve [Al₁₂P₁₃O₅₂]^3-[(CH₂)₆N₄H₃]³⁺, denoted AlPO-CJB1, which possesses Bronsted acidity upon removing the templates, is reported. The framework is constructed from strict alternation of Alcentered polyhedra (AlO₄ and AlO₅) and P-centered PO₄ tetrahedra by sharing oxygen atoms at vertices, which creates the anionic open-framework in contrast to previous AlPO(4-n) with neutral open-frameworks.

Original language	English (US)
Pages (from-to)	2517-2519
Number of pages	3
Journal	Chemistry of Materials
Volume	12
Issue number	9
DOIs	https://doi.org/10.1021/cm000280h
State	Published - 2000
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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title = "[Al12P13O52]3-[(CH2)6N4H3]3+: An anionic aluminophosphate molecular sieve with bronsted acidity",

abstract = "The first anionic aluminophosphate molecular sieve [Al12P13O52]3-[(CH2)6N4H3]3+, denoted AlPO-CJB1, which possesses Bronsted acidity upon removing the templates, is reported. The framework is constructed from strict alternation of Alcentered polyhedra (AlO4 and AlO5) and P-centered PO4 tetrahedra by sharing oxygen atoms at vertices, which creates the anionic open-framework in contrast to previous AlPO(4-n) with neutral open-frameworks.",

author = "W. Yan and J. Yu and R. Xu and G. Zhu and F. Xiao and Y. Han and K. Sugiyama and O. Terasaki",

year = "2000",

doi = "10.1021/cm000280h",

language = "English (US)",

volume = "12",

pages = "2517--2519",

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T1 - [Al12P13O52]3-[(CH2)6N4H3]3+

T2 - An anionic aluminophosphate molecular sieve with bronsted acidity

AU - Yan, W.

AU - Yu, J.

AU - Xu, R.

AU - Zhu, G.

AU - Xiao, F.

AU - Han, Y.

AU - Sugiyama, K.

AU - Terasaki, O.

PY - 2000

Y1 - 2000

N2 - The first anionic aluminophosphate molecular sieve [Al12P13O52]3-[(CH2)6N4H3]3+, denoted AlPO-CJB1, which possesses Bronsted acidity upon removing the templates, is reported. The framework is constructed from strict alternation of Alcentered polyhedra (AlO4 and AlO5) and P-centered PO4 tetrahedra by sharing oxygen atoms at vertices, which creates the anionic open-framework in contrast to previous AlPO(4-n) with neutral open-frameworks.

AB - The first anionic aluminophosphate molecular sieve [Al12P13O52]3-[(CH2)6N4H3]3+, denoted AlPO-CJB1, which possesses Bronsted acidity upon removing the templates, is reported. The framework is constructed from strict alternation of Alcentered polyhedra (AlO4 and AlO5) and P-centered PO4 tetrahedra by sharing oxygen atoms at vertices, which creates the anionic open-framework in contrast to previous AlPO(4-n) with neutral open-frameworks.

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U2 - 10.1021/cm000280h

DO - 10.1021/cm000280h

M3 - Article

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SN - 0897-4756

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SP - 2517

EP - 2519

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 9

ER -

[Al₁₂P₁₃O₅₂]^3-[(CH₂)₆N₄H₃]³⁺: An anionic aluminophosphate molecular sieve with bronsted acidity

Abstract

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