Alkane activation by a highly electrophilic zirconium hydride complex supported on silica

Francoise Quignard; Agnés Choplin; Jean-Marie Maurice Basset

doi:10.1039/C39910001589

Alkane activation by a highly electrophilic zirconium hydride complex supported on silica

Francoise Quignard^*, Agnés Choplin, Jean-Marie Maurice Basset

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The silica-grafted zirconium hydride complex, synthesized by hydrogenolysis of the well-defined 3 bonds of the lefthand side signSiOZrNp ₃ , activates the C-H bonds of cyclooctane and methane as shown by the formation of the corresponding cyclooctyl-and methyl-zirconium complexes.

Original language	English (US)
Pages (from-to)	1589-1590
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/C39910001589
State	Published - Jan 1 1991

ASJC Scopus subject areas

Molecular Medicine

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@article{17faeeeb187241f4940c2629de135824,

title = "Alkane activation by a highly electrophilic zirconium hydride complex supported on silica",

abstract = " The silica-grafted zirconium hydride complex, synthesized by hydrogenolysis of the well-defined 3 bonds of the lefthand side signSiOZrNp 3 , activates the C-H bonds of cyclooctane and methane as shown by the formation of the corresponding cyclooctyl-and methyl-zirconium complexes. ",

author = "Francoise Quignard and Agn{\'e}s Choplin and Basset, {Jean-Marie Maurice}",

year = "1991",

month = jan,

day = "1",

doi = "10.1039/C39910001589",

language = "English (US)",

pages = "1589--1590",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0577-6171",

publisher = "Chemical Society",

number = "22",

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TY - JOUR

T1 - Alkane activation by a highly electrophilic zirconium hydride complex supported on silica

AU - Quignard, Francoise

AU - Choplin, Agnés

AU - Basset, Jean-Marie Maurice

PY - 1991/1/1

Y1 - 1991/1/1

N2 - The silica-grafted zirconium hydride complex, synthesized by hydrogenolysis of the well-defined 3 bonds of the lefthand side signSiOZrNp 3 , activates the C-H bonds of cyclooctane and methane as shown by the formation of the corresponding cyclooctyl-and methyl-zirconium complexes.

AB - The silica-grafted zirconium hydride complex, synthesized by hydrogenolysis of the well-defined 3 bonds of the lefthand side signSiOZrNp 3 , activates the C-H bonds of cyclooctane and methane as shown by the formation of the corresponding cyclooctyl-and methyl-zirconium complexes.

UR - http://www.scopus.com/inward/record.url?scp=37049072747&partnerID=8YFLogxK

U2 - 10.1039/C39910001589

DO - 10.1039/C39910001589

M3 - Article

AN - SCOPUS:37049072747

SN - 0577-6171

SP - 1589

EP - 1590

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 22

ER -

Alkane activation by a highly electrophilic zirconium hydride complex supported on silica

Abstract

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