Advantageous 3D ordering of π-conjugated systems: A new approach towards efficient charge transport in any direction: A new approach towards efficient charge transport in any direction

Hao Pang; Filipe Vilela; Peter J. Skabara; Joseph J.W. McDouall; David J. Crouch; Thomas D. Anthopoulos; Donal D.C. Bradley; Dago M. De Leeuw; Peter N. Horton; Michael B. Hursthouse

doi:10.1002/adma.200702135

Advantageous 3D ordering of π-conjugated systems: A new approach towards efficient charge transport in any direction: A new approach towards efficient charge transport in any direction

Hao Pang, Filipe Vilela, Peter J. Skabara, Joseph J.W. McDouall, David J. Crouch, Thomas D. Anthopoulos, Donal D.C. Bradley, Dago M. De Leeuw, Peter N. Horton, Michael B. Hursthouse

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

A new molecule, bis(hexylthieno)benzobisthiazole 1, which self-assembles in the solid state to give intermolecular close contacts in all three dimensions, is presented. This structure represents a highly promising new packing mode that eliminates the significant problem of manipulating molecular alignment within an OFET device, since charges will propagate efficiently between source and drain, irrespective of the orientation obtained during deposition. Higher values for hole mobility are probably restricted by the large difference between the HOMO of 1 and the work function of the gold electrode.

Original language	English (US)
Pages (from-to)	4438-4442
Number of pages	5
Journal	Advanced Materials
Volume	19
Issue number	24
DOIs	https://doi.org/10.1002/adma.200702135
State	Published - Dec 17 2007
Externally published	Yes

Bibliographical note

Generated from Scopus record by KAUST IRTS on 2019-11-27

ASJC Scopus subject areas

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

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10.1002/adma.200702135

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Pang, H., Vilela, F., Skabara, P. J., McDouall, J. J. W., Crouch, D. J., Anthopoulos, T. D., Bradley, D. D. C., De Leeuw, D. M., Horton, P. N., & Hursthouse, M. B. (2007). Advantageous 3D ordering of π-conjugated systems: A new approach towards efficient charge transport in any direction: A new approach towards efficient charge transport in any direction. Advanced Materials, 19(24), 4438-4442. https://doi.org/10.1002/adma.200702135

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title = "Advantageous 3D ordering of π-conjugated systems: A new approach towards efficient charge transport in any direction: A new approach towards efficient charge transport in any direction",

abstract = "A new molecule, bis(hexylthieno)benzobisthiazole 1, which self-assembles in the solid state to give intermolecular close contacts in all three dimensions, is presented. This structure represents a highly promising new packing mode that eliminates the significant problem of manipulating molecular alignment within an OFET device, since charges will propagate efficiently between source and drain, irrespective of the orientation obtained during deposition. Higher values for hole mobility are probably restricted by the large difference between the HOMO of 1 and the work function of the gold electrode.",

author = "Hao Pang and Filipe Vilela and Skabara, {Peter J.} and McDouall, {Joseph J.W.} and Crouch, {David J.} and Anthopoulos, {Thomas D.} and Bradley, {Donal D.C.} and {De Leeuw}, {Dago M.} and Horton, {Peter N.} and Hursthouse, {Michael B.}",

note = "Generated from Scopus record by KAUST IRTS on 2019-11-27",

year = "2007",

month = dec,

day = "17",

doi = "10.1002/adma.200702135",

language = "English (US)",

volume = "19",

pages = "4438--4442",

journal = "Advanced Materials",

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Pang, H, Vilela, F, Skabara, PJ, McDouall, JJW, Crouch, DJ, Anthopoulos, TD, Bradley, DDC, De Leeuw, DM, Horton, PN & Hursthouse, MB 2007, 'Advantageous 3D ordering of π-conjugated systems: A new approach towards efficient charge transport in any direction: A new approach towards efficient charge transport in any direction', Advanced Materials, vol. 19, no. 24, pp. 4438-4442. https://doi.org/10.1002/adma.200702135

Advantageous 3D ordering of π-conjugated systems: A new approach towards efficient charge transport in any direction : A new approach towards efficient charge transport in any direction. / Pang, Hao; Vilela, Filipe; Skabara, Peter J. et al.

In: Advanced Materials, Vol. 19, No. 24, 17.12.2007, p. 4438-4442.

Research output: Contribution to journal › Article › peer-review

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T2 - A new approach towards efficient charge transport in any direction

AU - Pang, Hao

AU - Vilela, Filipe

AU - Skabara, Peter J.

AU - McDouall, Joseph J.W.

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AU - Anthopoulos, Thomas D.

AU - Bradley, Donal D.C.

AU - De Leeuw, Dago M.

AU - Horton, Peter N.

AU - Hursthouse, Michael B.

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AB - A new molecule, bis(hexylthieno)benzobisthiazole 1, which self-assembles in the solid state to give intermolecular close contacts in all three dimensions, is presented. This structure represents a highly promising new packing mode that eliminates the significant problem of manipulating molecular alignment within an OFET device, since charges will propagate efficiently between source and drain, irrespective of the orientation obtained during deposition. Higher values for hole mobility are probably restricted by the large difference between the HOMO of 1 and the work function of the gold electrode.

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Advantageous 3D ordering of π-conjugated systems: A new approach towards efficient charge transport in any direction: A new approach towards efficient charge transport in any direction

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