Advances in allylic and benzylic C–H bond functionalization enabled by metallaphotoredox catalysis

Huifeng Yue; Chen Zhu; Long Huang; Abhishek Dewanji; Magnus Rueping

doi:10.1039/d1cc06285a

Advances in allylic and benzylic C–H bond functionalization enabled by metallaphotoredox catalysis

Huifeng Yue, Chen Zhu, Long Huang, Abhishek Dewanji, Magnus Rueping

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Metallaphoto-catalysis has been established as a robust platform for efficient construction of a range of chemical bonds. Moreover, transformation of native functionalities such as C(sp3)–H bonds to produce functional molecules represents one of the most attractive strategies in organic synthesis. Merging two powerful methodologies, metallaphoto-catalyzed benzylic and allylic C(sp3)–H bond functionalizations provide a series of general and mild approaches for diversification of alkylbenzenes and alkenes.

Original language	English (US)
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/d1cc06285a
State	Published - Dec 6 2021

Bibliographical note

KAUST Repository Item: Exported on 2021-12-13
Acknowledged KAUST grant number(s): URF/1/4384
Acknowledgements: This work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4384).

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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10.1039/d1cc06285a

https://repository.kaust.edu.sa/bitstream/10754/673992/1/d1cc06285a.pdf

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title = "Advances in allylic and benzylic C–H bond functionalization enabled by metallaphotoredox catalysis",

abstract = "Metallaphoto-catalysis has been established as a robust platform for efficient construction of a range of chemical bonds. Moreover, transformation of native functionalities such as C(sp3)–H bonds to produce functional molecules represents one of the most attractive strategies in organic synthesis. Merging two powerful methodologies, metallaphoto-catalyzed benzylic and allylic C(sp3)–H bond functionalizations provide a series of general and mild approaches for diversification of alkylbenzenes and alkenes.",

author = "Huifeng Yue and Chen Zhu and Long Huang and Abhishek Dewanji and Magnus Rueping",

note = "KAUST Repository Item: Exported on 2021-12-13 Acknowledged KAUST grant number(s): URF/1/4384 Acknowledgements: This work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4384).",

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AU - Yue, Huifeng

AU - Zhu, Chen

AU - Huang, Long

AU - Dewanji, Abhishek

AU - Rueping, Magnus

N1 - KAUST Repository Item: Exported on 2021-12-13 Acknowledged KAUST grant number(s): URF/1/4384 Acknowledgements: This work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4384).

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Y1 - 2021/12/6

N2 - Metallaphoto-catalysis has been established as a robust platform for efficient construction of a range of chemical bonds. Moreover, transformation of native functionalities such as C(sp3)–H bonds to produce functional molecules represents one of the most attractive strategies in organic synthesis. Merging two powerful methodologies, metallaphoto-catalyzed benzylic and allylic C(sp3)–H bond functionalizations provide a series of general and mild approaches for diversification of alkylbenzenes and alkenes.

AB - Metallaphoto-catalysis has been established as a robust platform for efficient construction of a range of chemical bonds. Moreover, transformation of native functionalities such as C(sp3)–H bonds to produce functional molecules represents one of the most attractive strategies in organic synthesis. Merging two powerful methodologies, metallaphoto-catalyzed benzylic and allylic C(sp3)–H bond functionalizations provide a series of general and mild approaches for diversification of alkylbenzenes and alkenes.

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UR - http://xlink.rsc.org/?DOI=D1CC06285A

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JO - Chemical Communications

JF - Chemical Communications

ER -

Advances in allylic and benzylic C–H bond functionalization enabled by metallaphotoredox catalysis

Abstract

Bibliographical note

ASJC Scopus subject areas

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