TY - JOUR
T1 - Adsorption-Driven Heat Pumps
T2 - The Potential of Metal-Organic Frameworks
AU - De Lange, Martijn F.
AU - Verouden, Karlijn J.F.M.
AU - Vlugt, Thijs J.H.
AU - Gascon Sabate, Jorge
AU - Kapteijn, Freek
PY - 2015/1/1
Y1 - 2015/1/1
N2 - The potential of metal-organic frameworks (MOFs) for adsorption-driven heat pumps is discussed. Three different mechanisms for water adsorption in MOFs can be distinguished, such as adsorption on the metallic cluster, which modifies the first coordination sphere of the metal ion, layer or cluster adsorption in pores, and capillary condensation in pores. Cluster adsorption is prevalent over layer formation when water is concerned, as most MOFs consist of aromatic ligands, which are hydrophobic in nature.
AB - The potential of metal-organic frameworks (MOFs) for adsorption-driven heat pumps is discussed. Three different mechanisms for water adsorption in MOFs can be distinguished, such as adsorption on the metallic cluster, which modifies the first coordination sphere of the metal ion, layer or cluster adsorption in pores, and capillary condensation in pores. Cluster adsorption is prevalent over layer formation when water is concerned, as most MOFs consist of aromatic ligands, which are hydrophobic in nature.
UR - http://www.scopus.com/inward/record.url?scp=84947965483&partnerID=8YFLogxK
U2 - 10.1021/acs.chemrev.5b00059
DO - 10.1021/acs.chemrev.5b00059
M3 - Review article
AN - SCOPUS:84947965483
SN - 0009-2665
VL - 115
SP - 12205
EP - 12250
JO - Chemical Reviews
JF - Chemical Reviews
IS - 22
ER -