Activity enhancement via borate incorporation into a NiFe (oxy)hydroxide catalyst for electrocatalytic oxygen evolution

Ning Wang, Zhen Cao, Xiangbin Kong, Junhui Liang, Qixing Zhang, Lirong Zheng, Changchun Wei, Xinliang Chen, Ying Zhao, Luigi Cavallo, Bo Zhang, Xiaodan Zhang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

21 Scopus citations


The oxygen evolution reaction (OER) is a key process in electrocatalysis and is critical for achieving the cost-effective conversion of renewable electricity to chemicals and fuels. However, the high overpotential (η) originates from poor charge-transfer ability and low catalytic activity may lead to high power consumption. Herein, we alleviate these issues by introducing borate into the NiFe (oxy)hydroxide framework. Our density functional theory (DFT) calculations demonstrated that the borate could be efficiently adsorbed onto the Ni/NiFe (oxy)hydroxide surface. Microscopically, the adsorbed borate can induce a favorable electronic structure for the Ni active sites. Meanwhile, the macroscopic charge-transfer ability of this synthesized catalyst has been dramatically increased. Hence, the catalytic performance of this material is improved compared with its NiFe counterpart: we achieved a higher OER activity with an ultralow η of only 230 mV at 10 mA cm-2 on a glassy carbon electrode (GCE) and of 200 mV at 10 mA cm-2 on Ni foam in alkaline medium. Moreover, this borate mediated NiFe (oxy)hydroxide is very stable: no appreciable degradation is observed after more than 110 hours of operation.

Original languageEnglish (US)
Pages (from-to)16959-16964
Number of pages6
Issue number35
StatePublished - 2018

Bibliographical note

Publisher Copyright:
© 2018 The Royal Society of Chemistry.

ASJC Scopus subject areas

  • General Chemistry
  • Renewable Energy, Sustainability and the Environment
  • General Materials Science


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