Activation and functionalisation of the C-H bonds of methane and higher alkanes by a silica-supported tantalum hydride complex

Véronique Vidal; Albert Théolier; Jean Thivolle-Cazat; Jean Marie Basset

doi:10.1039/C39950000991

Activation and functionalisation of the C-H bonds of methane and higher alkanes by a silica-supported tantalum hydride complex

Véronique Vidal, Albert Théolier, Jean Thivolle-Cazat, Jean Marie Basset^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Silica-supported tantalum hydride activates at low temperature the C-H and the C-D bonds of cyclooctane and CD₄, respectively, to form the corresponding cyclooctyl and perdeuteriomethyl-tantalum surface complexes; these complexes are transformed under molecular oxygen into the corresponding tantalum-alkoxy derivatives which with acetic acid give rise to the corresponding alkylacetates.

Original language	English (US)
Pages (from-to)	991-992
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39950000991
State	Published - 1995
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Activation and functionalisation of the C-H bonds of methane and higher alkanes by a silica-supported tantalum hydride complex",

abstract = "Silica-supported tantalum hydride activates at low temperature the C-H and the C-D bonds of cyclooctane and CD4, respectively, to form the corresponding cyclooctyl and perdeuteriomethyl-tantalum surface complexes; these complexes are transformed under molecular oxygen into the corresponding tantalum-alkoxy derivatives which with acetic acid give rise to the corresponding alkylacetates.",

author = "V{\'e}ronique Vidal and Albert Th{\'e}olier and Jean Thivolle-Cazat and Basset, {Jean Marie}",

year = "1995",

doi = "10.1039/C39950000991",

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pages = "991--992",

journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - Activation and functionalisation of the C-H bonds of methane and higher alkanes by a silica-supported tantalum hydride complex

AU - Vidal, Véronique

AU - Théolier, Albert

AU - Thivolle-Cazat, Jean

AU - Basset, Jean Marie

PY - 1995

Y1 - 1995

N2 - Silica-supported tantalum hydride activates at low temperature the C-H and the C-D bonds of cyclooctane and CD4, respectively, to form the corresponding cyclooctyl and perdeuteriomethyl-tantalum surface complexes; these complexes are transformed under molecular oxygen into the corresponding tantalum-alkoxy derivatives which with acetic acid give rise to the corresponding alkylacetates.

AB - Silica-supported tantalum hydride activates at low temperature the C-H and the C-D bonds of cyclooctane and CD4, respectively, to form the corresponding cyclooctyl and perdeuteriomethyl-tantalum surface complexes; these complexes are transformed under molecular oxygen into the corresponding tantalum-alkoxy derivatives which with acetic acid give rise to the corresponding alkylacetates.

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U2 - 10.1039/C39950000991

DO - 10.1039/C39950000991

M3 - Article

AN - SCOPUS:37049077284

SN - 0022-4936

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 10

ER -

Activation and functionalisation of the C-H bonds of methane and higher alkanes by a silica-supported tantalum hydride complex

Abstract

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