A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis–alkyl transfer mechanism

Jérémie Pelletier, Jeff Espinas, Nghiem Vu, Sébastien Norsic, Anne Baudouin, Laurent Delevoye, Julien Trébosc, Erwan Le Roux, Catherine Santini, Jean-Marie Basset, Régis M. Gauvin, Mostafa Taoufik

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47 Scopus citations

Abstract

Impregnation of [(AliBu3)(Et2O)] on partially dehydroxylated SBA-15 affords a mesoporous material bearing the well-defined single site surface aluminium species [(≡SiO)2Al(iBu)(Et 2O)]. © The Royal Society of Chemistry.
Original languageEnglish (US)
Pages (from-to)2979
JournalChemical Communications
Volume47
Issue number10
DOIs
StatePublished - 2011

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work was supported by CNRS and the French Government through the "MATCALCAT'' ANR Project (contract ANR 07-CP2D-21-02), the Competitiveness Cluster on Chemistry and Environment of Lyon1 Rhone-Alpes (Axelera) and the TGE RMN THC Fr3050. E. L. R. thanks the Nanoscience program@UiB for generous support.

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