A tailored organometallic-inorganic hybrid mesostructured material: A route to a well-defined, active, and reusable heterogeneous iridium-NHC catalyst for H/D exchange

Tarun K. Maishal; Johan Alauzun; Jean Marie Basset; Christophe Copéret; Robert J.P. Corriu; Erwan Jeanneau; Ahmad Mehdi; Catherine Reyé; Laurent Veyre; Chloé Thieuleux

doi:10.1002/anie.200802956

A tailored organometallic-inorganic hybrid mesostructured material: A route to a well-defined, active, and reusable heterogeneous iridium-NHC catalyst for H/D exchange

Tarun K. Maishal, Johan Alauzun, Jean Marie Basset, Christophe Copéret, Robert J.P. Corriu, Erwan Jeanneau, Ahmad Mehdi, Catherine Reyé, Laurent Veyre, Chloé Thieuleux

Research output: Contribution to journal › Article › peer-review

76 Scopus citations

Abstract

(Chemical Equation Presented) A tailored hybrid mesostructured material containing regularly distributed imidazolium units, and subsequent transformation of these imidazolium moieties into Ir-NHC (NHC = N-heterocyclic carbene) complexes via the formation of Ag-NHC species in situ and further transmetalation with [{IrCp*Cl₂}₂], gives a well-defined, active,and reusable Ir-NHC heterogeneous catalyst for H/D exchange reactions (see picture).

Original language	English (US)
Pages (from-to)	8654-8656
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	45
DOIs	https://doi.org/10.1002/anie.200802956
State	Published - Oct 27 2008
Externally published	Yes

Keywords

Deuterium
Heterogeneous catalysis
Hybrid materials
Iridium
Sol-gel processes

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200802956

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Maishal, T. K., Alauzun, J., Basset, J. M., Copéret, C., Corriu, R. J. P., Jeanneau, E., Mehdi, A., Reyé, C., Veyre, L., & Thieuleux, C. (2008). A tailored organometallic-inorganic hybrid mesostructured material: A route to a well-defined, active, and reusable heterogeneous iridium-NHC catalyst for H/D exchange. Angewandte Chemie - International Edition, 47(45), 8654-8656. https://doi.org/10.1002/anie.200802956

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title = "A tailored organometallic-inorganic hybrid mesostructured material: A route to a well-defined, active, and reusable heterogeneous iridium-NHC catalyst for H/D exchange",

abstract = "(Chemical Equation Presented) A tailored hybrid mesostructured material containing regularly distributed imidazolium units, and subsequent transformation of these imidazolium moieties into Ir-NHC (NHC = N-heterocyclic carbene) complexes via the formation of Ag-NHC species in situ and further transmetalation with [{IrCp*Cl2}2], gives a well-defined, active,and reusable Ir-NHC heterogeneous catalyst for H/D exchange reactions (see picture).",

keywords = "Deuterium, Heterogeneous catalysis, Hybrid materials, Iridium, Sol-gel processes",

author = "Maishal, {Tarun K.} and Johan Alauzun and Basset, {Jean Marie} and Christophe Cop{\'e}ret and Corriu, {Robert J.P.} and Erwan Jeanneau and Ahmad Mehdi and Catherine Rey{\'e} and Laurent Veyre and Chlo{\'e} Thieuleux",

year = "2008",

month = oct,

day = "27",

doi = "10.1002/anie.200802956",

language = "English (US)",

volume = "47",

pages = "8654--8656",

journal = "Angewandte Chemie - International Edition",

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}

Maishal, TK, Alauzun, J, Basset, JM, Copéret, C, Corriu, RJP, Jeanneau, E, Mehdi, A, Reyé, C, Veyre, L & Thieuleux, C 2008, 'A tailored organometallic-inorganic hybrid mesostructured material: A route to a well-defined, active, and reusable heterogeneous iridium-NHC catalyst for H/D exchange', Angewandte Chemie - International Edition, vol. 47, no. 45, pp. 8654-8656. https://doi.org/10.1002/anie.200802956

A tailored organometallic-inorganic hybrid mesostructured material: A route to a well-defined, active, and reusable heterogeneous iridium-NHC catalyst for H/D exchange. / Maishal, Tarun K.; Alauzun, Johan; Basset, Jean Marie et al.
In: Angewandte Chemie - International Edition, Vol. 47, No. 45, 27.10.2008, p. 8654-8656.

Research output: Contribution to journal › Article › peer-review

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T1 - A tailored organometallic-inorganic hybrid mesostructured material

T2 - A route to a well-defined, active, and reusable heterogeneous iridium-NHC catalyst for H/D exchange

AU - Maishal, Tarun K.

AU - Alauzun, Johan

AU - Basset, Jean Marie

AU - Copéret, Christophe

AU - Corriu, Robert J.P.

AU - Jeanneau, Erwan

AU - Mehdi, Ahmad

AU - Reyé, Catherine

AU - Veyre, Laurent

AU - Thieuleux, Chloé

PY - 2008/10/27

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KW - Deuterium

KW - Heterogeneous catalysis

KW - Hybrid materials

KW - Iridium

KW - Sol-gel processes

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A tailored organometallic-inorganic hybrid mesostructured material: A route to a well-defined, active, and reusable heterogeneous iridium-NHC catalyst for H/D exchange

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Keywords

ASJC Scopus subject areas

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