A simple method for controlling dendritic architecture and diversity: A parallel monomer combination approach

A. W. Freeman; L. A.J. Chrisstoffels; J. M.J. Frechet

doi:10.1021/jo005592i

A simple method for controlling dendritic architecture and diversity: A parallel monomer combination approach

A. W. Freeman, L. A.J. Chrisstoffels, J. M.J. Frechet^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

A novel parallel monomer combination approach to manipulating the architectural disposition of dendritic macromolecules is described. It harnesses the synthetic speed and power of the double-stage convergent growth approach and classical parallel synthesis to prepare diverse series of dendrimers that possess a predetermined number and arrangement of 'internal' functional moieties. This methodology is applied for the preparation of a novel family of poly(benzyl ether) dendrimers possessing 1-15 'internal' allyloxy groups, which are displayed in a highly controlled, layer-specific, generational manner.

Original language	English (US)
Pages (from-to)	7612-7617
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	65
Issue number	22
DOIs	https://doi.org/10.1021/jo005592i
State	Published - Nov 3 2000
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo005592i

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title = "A simple method for controlling dendritic architecture and diversity: A parallel monomer combination approach",

abstract = "A novel parallel monomer combination approach to manipulating the architectural disposition of dendritic macromolecules is described. It harnesses the synthetic speed and power of the double-stage convergent growth approach and classical parallel synthesis to prepare diverse series of dendrimers that possess a predetermined number and arrangement of 'internal' functional moieties. This methodology is applied for the preparation of a novel family of poly(benzyl ether) dendrimers possessing 1-15 'internal' allyloxy groups, which are displayed in a highly controlled, layer-specific, generational manner.",

author = "Freeman, {A. W.} and Chrisstoffels, {L. A.J.} and Frechet, {J. M.J.}",

year = "2000",

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AU - Frechet, J. M.J.

PY - 2000/11/3

Y1 - 2000/11/3

N2 - A novel parallel monomer combination approach to manipulating the architectural disposition of dendritic macromolecules is described. It harnesses the synthetic speed and power of the double-stage convergent growth approach and classical parallel synthesis to prepare diverse series of dendrimers that possess a predetermined number and arrangement of 'internal' functional moieties. This methodology is applied for the preparation of a novel family of poly(benzyl ether) dendrimers possessing 1-15 'internal' allyloxy groups, which are displayed in a highly controlled, layer-specific, generational manner.

AB - A novel parallel monomer combination approach to manipulating the architectural disposition of dendritic macromolecules is described. It harnesses the synthetic speed and power of the double-stage convergent growth approach and classical parallel synthesis to prepare diverse series of dendrimers that possess a predetermined number and arrangement of 'internal' functional moieties. This methodology is applied for the preparation of a novel family of poly(benzyl ether) dendrimers possessing 1-15 'internal' allyloxy groups, which are displayed in a highly controlled, layer-specific, generational manner.

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M3 - Article

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ER -

A simple method for controlling dendritic architecture and diversity: A parallel monomer combination approach

Abstract

ASJC Scopus subject areas

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