A sensitivity study of the oxidation of compressed natural gas on platinum

Jihad Badra, Assaad Rachid Masri, Aamir Farooq

Research output: Contribution to journalArticlepeer-review

4 Scopus citations


This paper presents a sensitivity study for the oxidation of methane (CH4) over platinum (Pt). Some dominant reactions in the CH 4-Pt surface chemistry were identified and the rates of these reactions were subsequently modified to enhance the calculations. Initially, a range of CH4-Pt surface mechanisms available in the literature are used, along with the relevant detailed gaseous chemistry to compute the structure of premixed compressed natural gas (CNG)/air flames co-flowing around a flat, vertical, unconfined, rectangular, and platinum plate. Comparison with existing measurements of surface temperature and species concentrations revealed significant discrepancies for all mechanisms. Sensitivity analysis has identified nine key reactions which dominate the heterogeneous chemistry of methane over platinum. The rates of these reactions were modified over a reasonable range and in different combinations leading to an "optimal" mechanism for methane/air surface chemistry on platinum. The new mechanism is then used with the same flow geometry for different cases varying the temperature of the incoming mixture (Tjet), its equivalence ratio (Φ) and the Reynolds number (Re). Results from the modified surface mechanism demonstrate reasonably good agreement with the experimental data for a wide range of operating conditions. © 2013 Elsevier Ltd. All rights reserved.
Original languageEnglish (US)
Pages (from-to)467-480
Number of pages14
StatePublished - Nov 2013

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The experimental part of this work was supported by the Australian Research Council. Additional funding was provided by the Clean Combustion Research Center and King Abdullah University of Science and Technology.

ASJC Scopus subject areas

  • Energy Engineering and Power Technology
  • Organic Chemistry
  • General Chemical Engineering
  • Fuel Technology


Dive into the research topics of 'A sensitivity study of the oxidation of compressed natural gas on platinum'. Together they form a unique fingerprint.

Cite this