A Novel [OSSO]-Type Chromium(III) Complex as a Versatile Catalyst for Copolymerization of Carbon Dioxide with Epoxides

Francesco Della Monica; Veronica Paradiso; Alfonso Grassi; Stefano Milione; Luigi Cavallo; Carmine Capacchione

doi:10.1002/chem.201905455

A Novel [OSSO]-Type Chromium(III) Complex as a Versatile Catalyst for Copolymerization of Carbon Dioxide with Epoxides

Francesco Della Monica, Veronica Paradiso, Alfonso Grassi, Stefano Milione, Luigi Cavallo, Carmine Capacchione^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A new chromium(III) complex, bearing a bis-thioether-diphenolate [OSSO]-type ligand, was found to be an efficient catalyst in the copolymerization of CO₂ and epoxides to achieve poly(propylene carbonate), poly(cyclohexene carbonate), poly(hexene carbonate) and poly(styrene carbonate), as well as poly(propylene carbonate)(cyclohexene carbonate) and poly(propylene carbonate)(hexene carbonate) terpolymers.

Original language	English (US)
Pages (from-to)	5347-5353
Number of pages	7
Journal	Chemistry - A European Journal
Volume	26
Issue number	24
DOIs	https://doi.org/10.1002/chem.201905455
State	Published - Apr 24 2020

Bibliographical note

Publisher Copyright:
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

biopolymers
carbon dioxide
chromium
homogeneous catalysis
polycarbonates

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.201905455

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title = "A Novel [OSSO]-Type Chromium(III) Complex as a Versatile Catalyst for Copolymerization of Carbon Dioxide with Epoxides",

abstract = "A new chromium(III) complex, bearing a bis-thioether-diphenolate [OSSO]-type ligand, was found to be an efficient catalyst in the copolymerization of CO2 and epoxides to achieve poly(propylene carbonate), poly(cyclohexene carbonate), poly(hexene carbonate) and poly(styrene carbonate), as well as poly(propylene carbonate)(cyclohexene carbonate) and poly(propylene carbonate)(hexene carbonate) terpolymers.",

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author = "{Della Monica}, Francesco and Veronica Paradiso and Alfonso Grassi and Stefano Milione and Luigi Cavallo and Carmine Capacchione",

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AU - Della Monica, Francesco

AU - Paradiso, Veronica

AU - Grassi, Alfonso

AU - Milione, Stefano

AU - Cavallo, Luigi

AU - Capacchione, Carmine

PY - 2020/4/24

Y1 - 2020/4/24

N2 - A new chromium(III) complex, bearing a bis-thioether-diphenolate [OSSO]-type ligand, was found to be an efficient catalyst in the copolymerization of CO2 and epoxides to achieve poly(propylene carbonate), poly(cyclohexene carbonate), poly(hexene carbonate) and poly(styrene carbonate), as well as poly(propylene carbonate)(cyclohexene carbonate) and poly(propylene carbonate)(hexene carbonate) terpolymers.

AB - A new chromium(III) complex, bearing a bis-thioether-diphenolate [OSSO]-type ligand, was found to be an efficient catalyst in the copolymerization of CO2 and epoxides to achieve poly(propylene carbonate), poly(cyclohexene carbonate), poly(hexene carbonate) and poly(styrene carbonate), as well as poly(propylene carbonate)(cyclohexene carbonate) and poly(propylene carbonate)(hexene carbonate) terpolymers.

KW - biopolymers

KW - carbon dioxide

KW - chromium

KW - homogeneous catalysis

KW - polycarbonates

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

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ER -

A Novel [OSSO]-Type Chromium(III) Complex as a Versatile Catalyst for Copolymerization of Carbon Dioxide with Epoxides

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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