A novel low-bandgap pyridazine thiadiazole-based conjugated polymer with deep molecular orbital levels

A. Leventis, T. N. Chmovzh, E. A. Knyazeva, Y. Han, M. Heeney, O. A. Rakitin, H. Bronstein

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

A pyridazine thiadiazole acceptor (PzT) has been utilised in the synthesis of a novel low band-gap D-A copolymer PTTPz. It is a much stronger acceptor in comparison to BT and PyT moieties widely incorporated in the literature. Experimental results reveal that per electronegative N atom that is substituted into the acceptor, an effective HOMO and LUMO stabilization energy of ∼0.2-0.1 eV can be achieved.
Original languageEnglish (US)
Pages (from-to)581-585
Number of pages5
JournalPolymer Chemistry
Volume11
Issue number2
DOIs
StatePublished - Jan 14 2020
Externally publishedYes

Bibliographical note

Generated from Scopus record by KAUST IRTS on 2023-02-14

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Biomedical Engineering
  • Bioengineering
  • Polymers and Plastics

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