A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope

Lee Richmond; Yuanyong Yang; Geok Kheng Tan; Choon Hong Tan; Kuo Wei Huang

doi:10.1039/b915881b

A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope

Lee Richmond, Yuanyong Yang, Geok Kheng Tan, Choon Hong Tan^*, Kuo Wei Huang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A novel paddlewheel or 'lantern' heteroleptic diruthenium guanidinate complex Ru₂(TBO)₂(OAc)₂Cl·3MeCN (1·3MeCN) was synthesized and structurally characterized. Compared with a known tetra-substituted di-ruthenium guanidinate complex Ru₂(TBD) ₄Cl, 1 revealed structural dissimilarities with internal twisting.

Original language	English (US)
Pages (from-to)	723-725
Number of pages	3
Journal	Dalton transactions
Volume	39
Issue number	3
DOIs	https://doi.org/10.1039/b915881b
State	Published - 2010

ASJC Scopus subject areas

Inorganic Chemistry

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title = "A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope",

abstract = "A novel paddlewheel or 'lantern' heteroleptic diruthenium guanidinate complex Ru2(TBO)2(OAc)2Cl·3MeCN (1·3MeCN) was synthesized and structurally characterized. Compared with a known tetra-substituted di-ruthenium guanidinate complex Ru2(TBD) 4Cl, 1 revealed structural dissimilarities with internal twisting.",

author = "Lee Richmond and Yuanyong Yang and Tan, {Geok Kheng} and Tan, {Choon Hong} and Huang, {Kuo Wei}",

year = "2010",

doi = "10.1039/b915881b",

language = "English (US)",

volume = "39",

pages = "723--725",

journal = "Dalton transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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T2 - Synthesis, structure, and scope

AU - Richmond, Lee

AU - Yang, Yuanyong

AU - Tan, Geok Kheng

AU - Tan, Choon Hong

AU - Huang, Kuo Wei

PY - 2010

Y1 - 2010

N2 - A novel paddlewheel or 'lantern' heteroleptic diruthenium guanidinate complex Ru2(TBO)2(OAc)2Cl·3MeCN (1·3MeCN) was synthesized and structurally characterized. Compared with a known tetra-substituted di-ruthenium guanidinate complex Ru2(TBD) 4Cl, 1 revealed structural dissimilarities with internal twisting.

AB - A novel paddlewheel or 'lantern' heteroleptic diruthenium guanidinate complex Ru2(TBO)2(OAc)2Cl·3MeCN (1·3MeCN) was synthesized and structurally characterized. Compared with a known tetra-substituted di-ruthenium guanidinate complex Ru2(TBD) 4Cl, 1 revealed structural dissimilarities with internal twisting.

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DO - 10.1039/b915881b

M3 - Article

C2 - 20066216

AN - SCOPUS:77149163446

SN - 1477-9226

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SP - 723

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JO - Dalton transactions

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A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope

Abstract

ASJC Scopus subject areas

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