A new 2D honeycomb-like cluster polymer built by a {Mn6Na 3} cluster: Synthesis and magnetic property

Yun En Xie, Chong Bing Tian, Hua Bin Zhang, Yan Peng, Xian Qiang Li, Zhi Hua Li, Ping Lin, Shao Wu Du

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

A new 2D polymer, {[Mn6Na3(μ6-O)(thme) 4(PhCO2)6(μ-H2O) 3][OH]}n (1), has been synthesized and characterized by single crystal X-ray diffraction, XRD, IR spectroscopy, thermogravimetric analysis (TGA) and magnetic measurements. Compound 1 has a 2D honeycomb-like structure constructed by heterometallic {Mn6Na3} clusters, which are linked by water molecules cross-bridged between the Na (I) ions of the adjacent clusters. Magnetic property study reveals the existence of antiferromagnetic couplings between Mn (III) ions within the {Mn 6Na3} clusters. © 2011 Elsevier B.V. All rights reserved.
Original languageEnglish (US)
Pages (from-to)198-201
Number of pages4
JournalInorganic Chemistry Communications
Volume15
DOIs
StatePublished - Jan 1 2012
Externally publishedYes

ASJC Scopus subject areas

  • Materials Chemistry
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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