A nanoplasmonic switch based on molecular machines

Yue Bing Zheng; Ying-Wei Yang; Lasse Jensen; Lei Fang; Bala Krishna Juluri; Paul S. Weiss; J. Fraser Stoddart; Tony Jun Huang

doi:10.1109/SENSOR.2009.5285604

A nanoplasmonic switch based on molecular machines

Yue Bing Zheng, Ying-Wei Yang, Lasse Jensen, Lei Fang, Bala Krishna Juluri, Paul S. Weiss, J. Fraser Stoddart, Tony Jun Huang

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

We aim to develop a molecular-machine-driven nanoplasmonic switch for its use in future nanophotonic integrated circuits (ICs) that have applications in optical communication, information processing, biological and chemical sensing. Experimental data show that an Au nanodisk array, coated with rotaxane molecular machines, switches its localized surface plasmon resonances (LSPR) reversibly when it is exposed to chemical oxidants and reductants. Conversely, bare Au nanodisks and disks coated with mechanically inert control compounds, do not display the same switching behavior. Along with calculations based on time-dependent density functional theory (TDDFT), these observations suggest that the nanoscale movements within surface-bound "molecular machines" can be used as the active components in plasmonic devices. ©2009 IEEE.

Original language	English (US)
Title of host publication	TRANSDUCERS 2009 - 2009 International Solid-State Sensors, Actuators and Microsystems Conference
Publisher	Institute of Electrical and Electronics Engineers (IEEE)
Pages	2160-2163
Number of pages	4
ISBN (Print)	9781424441907
DOIs	https://doi.org/10.1109/SENSOR.2009.5285604
State	Published - Jun 2009
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We thank Dr. Vincent Crespi for helpful discussions.This research was supported by the Air Force Office ofScientific Research, the National Science Foundation, andthe Penn State Center for Nanoscale Science.Components of this work were conducted at thePennsylvania State University node of the NSF-fundedNational Nanotechnology Infrastructure Network. YBZthanks the support from KAUST Scholar Award and theFounder’s Prize and Grant of the American Academy ofMechanics.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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10.1109/SENSOR.2009.5285604

Cite this

Zheng, Y. B., Yang, Y.-W., Jensen, L., Fang, L., Juluri, B. K., Weiss, P. S., Stoddart, J. F., & Huang, T. J. (2009). A nanoplasmonic switch based on molecular machines. In TRANSDUCERS 2009 - 2009 International Solid-State Sensors, Actuators and Microsystems Conference (pp. 2160-2163). Institute of Electrical and Electronics Engineers (IEEE). https://doi.org/10.1109/SENSOR.2009.5285604

@inproceedings{f38a1135937a4cc0921707fab4c9771d,

title = "A nanoplasmonic switch based on molecular machines",

abstract = "We aim to develop a molecular-machine-driven nanoplasmonic switch for its use in future nanophotonic integrated circuits (ICs) that have applications in optical communication, information processing, biological and chemical sensing. Experimental data show that an Au nanodisk array, coated with rotaxane molecular machines, switches its localized surface plasmon resonances (LSPR) reversibly when it is exposed to chemical oxidants and reductants. Conversely, bare Au nanodisks and disks coated with mechanically inert control compounds, do not display the same switching behavior. Along with calculations based on time-dependent density functional theory (TDDFT), these observations suggest that the nanoscale movements within surface-bound {"}molecular machines{"} can be used as the active components in plasmonic devices. {\textcopyright}2009 IEEE.",

author = "Zheng, {Yue Bing} and Ying-Wei Yang and Lasse Jensen and Lei Fang and Juluri, {Bala Krishna} and Weiss, {Paul S.} and Stoddart, {J. Fraser} and Huang, {Tony Jun}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We thank Dr. Vincent Crespi for helpful discussions.This research was supported by the Air Force Office ofScientific Research, the National Science Foundation, andthe Penn State Center for Nanoscale Science.Components of this work were conducted at thePennsylvania State University node of the NSF-fundedNational Nanotechnology Infrastructure Network. YBZthanks the support from KAUST Scholar Award and theFounder{\textquoteright}s Prize and Grant of the American Academy ofMechanics. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2009",

month = jun,

doi = "10.1109/SENSOR.2009.5285604",

language = "English (US)",

isbn = "9781424441907",

pages = "2160--2163",

booktitle = "TRANSDUCERS 2009 - 2009 International Solid-State Sensors, Actuators and Microsystems Conference",

publisher = "Institute of Electrical and Electronics Engineers (IEEE)",

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A nanoplasmonic switch based on molecular machines. / Zheng, Yue Bing; Yang, Ying-Wei; Jensen, Lasse et al.
TRANSDUCERS 2009 - 2009 International Solid-State Sensors, Actuators and Microsystems Conference. Institute of Electrical and Electronics Engineers (IEEE), 2009. p. 2160-2163.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

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AU - Stoddart, J. Fraser

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N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We thank Dr. Vincent Crespi for helpful discussions.This research was supported by the Air Force Office ofScientific Research, the National Science Foundation, andthe Penn State Center for Nanoscale Science.Components of this work were conducted at thePennsylvania State University node of the NSF-fundedNational Nanotechnology Infrastructure Network. YBZthanks the support from KAUST Scholar Award and theFounder’s Prize and Grant of the American Academy ofMechanics. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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N2 - We aim to develop a molecular-machine-driven nanoplasmonic switch for its use in future nanophotonic integrated circuits (ICs) that have applications in optical communication, information processing, biological and chemical sensing. Experimental data show that an Au nanodisk array, coated with rotaxane molecular machines, switches its localized surface plasmon resonances (LSPR) reversibly when it is exposed to chemical oxidants and reductants. Conversely, bare Au nanodisks and disks coated with mechanically inert control compounds, do not display the same switching behavior. Along with calculations based on time-dependent density functional theory (TDDFT), these observations suggest that the nanoscale movements within surface-bound "molecular machines" can be used as the active components in plasmonic devices. ©2009 IEEE.

AB - We aim to develop a molecular-machine-driven nanoplasmonic switch for its use in future nanophotonic integrated circuits (ICs) that have applications in optical communication, information processing, biological and chemical sensing. Experimental data show that an Au nanodisk array, coated with rotaxane molecular machines, switches its localized surface plasmon resonances (LSPR) reversibly when it is exposed to chemical oxidants and reductants. Conversely, bare Au nanodisks and disks coated with mechanically inert control compounds, do not display the same switching behavior. Along with calculations based on time-dependent density functional theory (TDDFT), these observations suggest that the nanoscale movements within surface-bound "molecular machines" can be used as the active components in plasmonic devices. ©2009 IEEE.

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DO - 10.1109/SENSOR.2009.5285604

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BT - TRANSDUCERS 2009 - 2009 International Solid-State Sensors, Actuators and Microsystems Conference

PB - Institute of Electrical and Electronics Engineers (IEEE)

ER -

A nanoplasmonic switch based on molecular machines

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