A multi-metal-cluster MOF with Cu4I4 and Cu6S6 as functional groups exhibiting dual emission with both thermochromic and near-IR character

Xiao Chen Shan; Fei Long Jiang; Da Qiang Yuan; Hua Bin Zhang; Ming Yan Wu; Lian Chen; Jing Wei; Shu Quan Zhang; Jie Pan; Mao Chun Hong

doi:10.1039/c3sc21995j

A multi-metal-cluster MOF with Cu4I4 and Cu6S6 as functional groups exhibiting dual emission with both thermochromic and near-IR character

Xiao Chen Shan, Fei Long Jiang, Da Qiang Yuan, Hua Bin Zhang, Ming Yan Wu, Lian Chen, Jing Wei, Shu Quan Zhang, Jie Pan, Mao Chun Hong

Research output: Contribution to journal › Article › peer-review

206 Scopus citations

Abstract

Two classical metal clusters, CuI4I4 and CuI6S6, are introduced as functional connecting nodes to construct a novel multi-metal-cluster MOF [(CuI4I4)3(CuI6)2(3-ptt)12]n·24nDEF·12nH2O (1) that incorporate their inherent luminescent properties, induced by their respective metal–metal interactions. These two distinct clusters are combined together for the first time to perform as functional luminophores that display unusual dual emission with both thermochromic luminescence and near-infrared (NIR) character. © 2013 The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	1484-1489
Number of pages	6
Journal	Chemical Science
Volume	4
Issue number	4
DOIs	https://doi.org/10.1039/c3sc21995j
State	Published - Mar 4 2013
Externally published	Yes

Bibliographical note

Generated from Scopus record by KAUST IRTS on 2022-09-15

ASJC Scopus subject areas

General Chemistry

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10.1039/c3sc21995j

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title = "A multi-metal-cluster MOF with Cu4I4 and Cu6S6 as functional groups exhibiting dual emission with both thermochromic and near-IR character",

abstract = "Two classical metal clusters, CuI4I4 and CuI6S6, are introduced as functional connecting nodes to construct a novel multi-metal-cluster MOF [(CuI4I4)3(CuI6)2(3-ptt)12]n·24nDEF·12nH2O (1) that incorporate their inherent luminescent properties, induced by their respective metal–metal interactions. These two distinct clusters are combined together for the first time to perform as functional luminophores that display unusual dual emission with both thermochromic luminescence and near-infrared (NIR) character. {\textcopyright} 2013 The Royal Society of Chemistry.",

author = "Shan, {Xiao Chen} and Jiang, {Fei Long} and Yuan, {Da Qiang} and Zhang, {Hua Bin} and Wu, {Ming Yan} and Lian Chen and Jing Wei and Zhang, {Shu Quan} and Jie Pan and Hong, {Mao Chun}",

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doi = "10.1039/c3sc21995j",

language = "English (US)",

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T1 - A multi-metal-cluster MOF with Cu4I4 and Cu6S6 as functional groups exhibiting dual emission with both thermochromic and near-IR character

AU - Shan, Xiao Chen

AU - Jiang, Fei Long

AU - Yuan, Da Qiang

AU - Zhang, Hua Bin

AU - Wu, Ming Yan

AU - Chen, Lian

AU - Wei, Jing

AU - Zhang, Shu Quan

AU - Pan, Jie

AU - Hong, Mao Chun

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15

PY - 2013/3/4

Y1 - 2013/3/4

N2 - Two classical metal clusters, CuI4I4 and CuI6S6, are introduced as functional connecting nodes to construct a novel multi-metal-cluster MOF [(CuI4I4)3(CuI6)2(3-ptt)12]n·24nDEF·12nH2O (1) that incorporate their inherent luminescent properties, induced by their respective metal–metal interactions. These two distinct clusters are combined together for the first time to perform as functional luminophores that display unusual dual emission with both thermochromic luminescence and near-infrared (NIR) character. © 2013 The Royal Society of Chemistry.

AB - Two classical metal clusters, CuI4I4 and CuI6S6, are introduced as functional connecting nodes to construct a novel multi-metal-cluster MOF [(CuI4I4)3(CuI6)2(3-ptt)12]n·24nDEF·12nH2O (1) that incorporate their inherent luminescent properties, induced by their respective metal–metal interactions. These two distinct clusters are combined together for the first time to perform as functional luminophores that display unusual dual emission with both thermochromic luminescence and near-infrared (NIR) character. © 2013 The Royal Society of Chemistry.

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U2 - 10.1039/c3sc21995j

DO - 10.1039/c3sc21995j

M3 - Article

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VL - 4

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JO - Chemical Science

JF - Chemical Science

IS - 4

ER -

A multi-metal-cluster MOF with Cu4I4 and Cu6S6 as functional groups exhibiting dual emission with both thermochromic and near-IR character

Abstract

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