A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues

Stephen Barlow; Chad Risko; Veaceslav Coropceanu; Neil M. Tucker; Simon C. Jones; Zerubba Levi; Viktor N. Khrustalev; Mikhail Yu Antipin; Tiffany L. Kinnibrugh; Tatiana Timofeeva; Seth R. Marder; Jean Luc Brédas

doi:10.1039/b415018j

A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues

Stephen Barlow^*, Chad Risko, Veaceslav Coropceanu, Neil M. Tucker, Simon C. Jones, Zerubba Levi, Viktor N. Khrustalev, Mikhail Yu Antipin, Tiffany L. Kinnibrugh, Tatiana Timofeeva, Seth R. Marder, Jean Luc Brédas

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

The E-4,4′-bis[di(p-anisyl)amino]stilbene cation is a class-III mixed-valence species with electronic coupling comparable to that in its biphenyl-bridged analogue, whereas its tolane-bridged analogue belongs to class II.

Original language	English (US)
Pages (from-to)	764-766
Number of pages	3
Journal	Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/b415018j
State	Published - Feb 14 2005
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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Barlow, S., Risko, C., Coropceanu, V., Tucker, N. M., Jones, S. C., Levi, Z., Khrustalev, V. N., Antipin, M. Y., Kinnibrugh, T. L., Timofeeva, T., Marder, S. R., & Brédas, J. L. (2005). A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues. Chemical Communications, (6), 764-766. https://doi.org/10.1039/b415018j

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abstract = "The E-4,4′-bis[di(p-anisyl)amino]stilbene cation is a class-III mixed-valence species with electronic coupling comparable to that in its biphenyl-bridged analogue, whereas its tolane-bridged analogue belongs to class II.",

author = "Stephen Barlow and Chad Risko and Veaceslav Coropceanu and Tucker, {Neil M.} and Jones, {Simon C.} and Zerubba Levi and Khrustalev, {Viktor N.} and Antipin, {Mikhail Yu} and Kinnibrugh, {Tiffany L.} and Tatiana Timofeeva and Marder, {Seth R.} and Br{\'e}das, {Jean Luc}",

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doi = "10.1039/b415018j",

language = "English (US)",

pages = "764--766",

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Barlow, S, Risko, C, Coropceanu, V, Tucker, NM, Jones, SC, Levi, Z, Khrustalev, VN, Antipin, MY, Kinnibrugh, TL, Timofeeva, T, Marder, SR & Brédas, JL 2005, 'A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues', Chemical Communications, no. 6, pp. 764-766. https://doi.org/10.1039/b415018j

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AU - Barlow, Stephen

AU - Risko, Chad

AU - Coropceanu, Veaceslav

AU - Tucker, Neil M.

AU - Jones, Simon C.

AU - Levi, Zerubba

AU - Khrustalev, Viktor N.

AU - Antipin, Mikhail Yu

AU - Kinnibrugh, Tiffany L.

AU - Timofeeva, Tatiana

AU - Marder, Seth R.

AU - Brédas, Jean Luc

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AB - The E-4,4′-bis[di(p-anisyl)amino]stilbene cation is a class-III mixed-valence species with electronic coupling comparable to that in its biphenyl-bridged analogue, whereas its tolane-bridged analogue belongs to class II.

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A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues

Abstract

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