A labile hydride strategy for the synthesis of heavily nitridized BaTiO3

Takeshi Yajima; Fumitaka Takeiri; Kohei Aidzu; Hirofumi Akamatsu; Koji Fujita; Wataru Yoshimune; Masatoshi Ohkura; Shiming Lei; Venkatraman Gopalan; Katsuhisa Tanaka; Craig M. Brown; Mark A. Green; Takafumi Yamamoto; Yoji Kobayashi; Hiroshi Kageyama

doi:10.1038/nchem.2370

A labile hydride strategy for the synthesis of heavily nitridized BaTiO3

Takeshi Yajima, Fumitaka Takeiri, Kohei Aidzu, Hirofumi Akamatsu, Koji Fujita, Wataru Yoshimune, Masatoshi Ohkura, Shiming Lei, Venkatraman Gopalan, Katsuhisa Tanaka, Craig M. Brown, Mark A. Green, Takafumi Yamamoto, Yoji Kobayashi, Hiroshi Kageyama

Research output: Contribution to journal › Article › peer-review

113 Scopus citations

Abstract

Oxynitrides have been explored extensively in the past decade because of their interesting properties, such as visible-light absorption, photocatalytic activity and high dielectric permittivity. Their synthesis typically requires high-temperature NH3 treatment (800-1,300 °C) of precursors, such as oxides, but the highly reducing conditions and the low mobility of N3- species in the lattice place significant constraints on the composition and structure-and hence the properties-of the resulting oxynitrides. Here we show a topochemical route that enables the preparation of an oxynitride at low temperatures (

Original language	English (US)
Pages (from-to)	1017-1023
Number of pages	7
Journal	Nature Chemistry
Volume	7
Issue number	12
DOIs	https://doi.org/10.1038/nchem.2370
State	Published - Dec 1 2015
Externally published	Yes

Bibliographical note

Generated from Scopus record by KAUST IRTS on 2022-09-13

ASJC Scopus subject areas

General Chemical Engineering
General Chemistry

Access to Document

10.1038/nchem.2370

Cite this

@article{73b29fd13ecf48b5bc4b85bb29a5036a,

title = "A labile hydride strategy for the synthesis of heavily nitridized BaTiO3",

abstract = "Oxynitrides have been explored extensively in the past decade because of their interesting properties, such as visible-light absorption, photocatalytic activity and high dielectric permittivity. Their synthesis typically requires high-temperature NH3 treatment (800-1,300 °C) of precursors, such as oxides, but the highly reducing conditions and the low mobility of N3- species in the lattice place significant constraints on the composition and structure-and hence the properties-of the resulting oxynitrides. Here we show a topochemical route that enables the preparation of an oxynitride at low temperatures (",

author = "Takeshi Yajima and Fumitaka Takeiri and Kohei Aidzu and Hirofumi Akamatsu and Koji Fujita and Wataru Yoshimune and Masatoshi Ohkura and Shiming Lei and Venkatraman Gopalan and Katsuhisa Tanaka and Brown, {Craig M.} and Green, {Mark A.} and Takafumi Yamamoto and Yoji Kobayashi and Hiroshi Kageyama",

note = "Generated from Scopus record by KAUST IRTS on 2022-09-13",

year = "2015",

month = dec,

day = "1",

doi = "10.1038/nchem.2370",

language = "English (US)",

volume = "7",

pages = "1017--1023",

journal = "Nature Chemistry",

issn = "1755-4349",

publisher = "Nature Publishing Group",

number = "12",

}

TY - JOUR

T1 - A labile hydride strategy for the synthesis of heavily nitridized BaTiO3

AU - Yajima, Takeshi

AU - Takeiri, Fumitaka

AU - Aidzu, Kohei

AU - Akamatsu, Hirofumi

AU - Fujita, Koji

AU - Yoshimune, Wataru

AU - Ohkura, Masatoshi

AU - Lei, Shiming

AU - Gopalan, Venkatraman

AU - Tanaka, Katsuhisa

AU - Brown, Craig M.

AU - Green, Mark A.

AU - Yamamoto, Takafumi

AU - Kobayashi, Yoji

AU - Kageyama, Hiroshi

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-13

PY - 2015/12/1

Y1 - 2015/12/1

N2 - Oxynitrides have been explored extensively in the past decade because of their interesting properties, such as visible-light absorption, photocatalytic activity and high dielectric permittivity. Their synthesis typically requires high-temperature NH3 treatment (800-1,300 °C) of precursors, such as oxides, but the highly reducing conditions and the low mobility of N3- species in the lattice place significant constraints on the composition and structure-and hence the properties-of the resulting oxynitrides. Here we show a topochemical route that enables the preparation of an oxynitride at low temperatures (

AB - Oxynitrides have been explored extensively in the past decade because of their interesting properties, such as visible-light absorption, photocatalytic activity and high dielectric permittivity. Their synthesis typically requires high-temperature NH3 treatment (800-1,300 °C) of precursors, such as oxides, but the highly reducing conditions and the low mobility of N3- species in the lattice place significant constraints on the composition and structure-and hence the properties-of the resulting oxynitrides. Here we show a topochemical route that enables the preparation of an oxynitride at low temperatures (

UR - http://www.nature.com/articles/nchem.2370

UR - http://www.scopus.com/inward/record.url?scp=84947724100&partnerID=8YFLogxK

U2 - 10.1038/nchem.2370

DO - 10.1038/nchem.2370

M3 - Article

SN - 1755-4349

VL - 7

SP - 1017

EP - 1023

JO - Nature Chemistry

JF - Nature Chemistry

IS - 12

ER -

A labile hydride strategy for the synthesis of heavily nitridized BaTiO3

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this