A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material

Huabin Zhang; Mingjian Zhang; Ping Lin; Victor Malgras; Jing Tang; Saad M. Alshehri; Yusuke Yamauchi; Shaowu Du; Jian Zhang

doi:10.1002/chem.201503561

A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material

Huabin Zhang, Mingjian Zhang, Ping Lin, Victor Malgras, Jing Tang, Saad M. Alshehri, Yusuke Yamauchi, Shaowu Du, Jian Zhang

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

Metal-organic framework (MOF)-based energetic material [Cu3(MA)2(N3)3] (1; MA=melamine) was synthesized and structurally characterized (47.55 % N). The structural analysis revealed the existence of unusual multiwalled tubular channels and interweaving of single and double helical units in 1. The standard molar enthalpy of formation was found to be 1788.73kJ mol-1, which is the highest value among previously reported MOF-based energetic materials. The calculated detonation properties showed that 1 can be used as a potential explosive. Sensitivity tests revealed that 1 is insensitive and thus can function as a high-energy-density material with a favorable level of safety.

Original language	English (US)
Pages (from-to)	1141-1145
Number of pages	5
Journal	Chemistry - A European Journal
Volume	22
Issue number	3
DOIs	https://doi.org/10.1002/chem.201503561
State	Published - Jan 18 2016
Externally published	Yes

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Generated from Scopus record by KAUST IRTS on 2022-09-15

ASJC Scopus subject areas

General Chemistry

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title = "A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material",

abstract = "Metal-organic framework (MOF)-based energetic material [Cu3(MA)2(N3)3] (1; MA=melamine) was synthesized and structurally characterized (47.55 % N). The structural analysis revealed the existence of unusual multiwalled tubular channels and interweaving of single and double helical units in 1. The standard molar enthalpy of formation was found to be 1788.73kJ mol-1, which is the highest value among previously reported MOF-based energetic materials. The calculated detonation properties showed that 1 can be used as a potential explosive. Sensitivity tests revealed that 1 is insensitive and thus can function as a high-energy-density material with a favorable level of safety.",

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T1 - A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material

AU - Zhang, Huabin

AU - Zhang, Mingjian

AU - Lin, Ping

AU - Malgras, Victor

AU - Tang, Jing

AU - Alshehri, Saad M.

AU - Yamauchi, Yusuke

AU - Du, Shaowu

AU - Zhang, Jian

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15

PY - 2016/1/18

Y1 - 2016/1/18

N2 - Metal-organic framework (MOF)-based energetic material [Cu3(MA)2(N3)3] (1; MA=melamine) was synthesized and structurally characterized (47.55 % N). The structural analysis revealed the existence of unusual multiwalled tubular channels and interweaving of single and double helical units in 1. The standard molar enthalpy of formation was found to be 1788.73kJ mol-1, which is the highest value among previously reported MOF-based energetic materials. The calculated detonation properties showed that 1 can be used as a potential explosive. Sensitivity tests revealed that 1 is insensitive and thus can function as a high-energy-density material with a favorable level of safety.

AB - Metal-organic framework (MOF)-based energetic material [Cu3(MA)2(N3)3] (1; MA=melamine) was synthesized and structurally characterized (47.55 % N). The structural analysis revealed the existence of unusual multiwalled tubular channels and interweaving of single and double helical units in 1. The standard molar enthalpy of formation was found to be 1788.73kJ mol-1, which is the highest value among previously reported MOF-based energetic materials. The calculated detonation properties showed that 1 can be used as a potential explosive. Sensitivity tests revealed that 1 is insensitive and thus can function as a high-energy-density material with a favorable level of safety.

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JF - Chemistry - A European Journal

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A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material

Abstract

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